Ro-vibrational spin-averaged transitions in the hydrogen molecular ions

Phys. Rev. A 104, 032806 (2021) We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loo...

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Main Authors Korobov, Vladimir I, Karr, Jean-Philippe
Format Journal Article
LanguageEnglish
Published 30.07.2021
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Abstract Phys. Rev. A 104, 032806 (2021) We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loop and two-loop QED corrections at $m\alpha^7$ and $m\alpha^8$ orders are recalculated in the framework of the adiabatic approximation, with systematic inclusion of corrections associated with vibrational motion. Improved theoretical transitions frequencies are obtained and found to be in very good agreement with recent high-precision spectroscopy experiments in HD$^+$. New values for the $m_p/m_e$ and $m_d/m_p$ mass ratios are determined.
AbstractList Phys. Rev. A 104, 032806 (2021) We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loop and two-loop QED corrections at $m\alpha^7$ and $m\alpha^8$ orders are recalculated in the framework of the adiabatic approximation, with systematic inclusion of corrections associated with vibrational motion. Improved theoretical transitions frequencies are obtained and found to be in very good agreement with recent high-precision spectroscopy experiments in HD$^+$. New values for the $m_p/m_e$ and $m_d/m_p$ mass ratios are determined.
Author Karr, Jean-Philippe
Korobov, Vladimir I
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BackLink https://doi.org/10.1103/PhysRevA.104.032806$$DView published paper (Access to full text may be restricted)
https://doi.org/10.48550/arXiv.2107.14497$$DView paper in arXiv
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Snippet Phys. Rev. A 104, 032806 (2021) We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected...
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Title Ro-vibrational spin-averaged transitions in the hydrogen molecular ions
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