Magnetic moments of short-lived nuclei with part-per-million accuracy: Towards novel applications of $\beta$-detected NMR in physics, chemistry and biology

• Main Authors: Harding, R. D, Pallada, S, Croese, J, Antušek, A. A, Baranowski, M, Bissell, M. L, Cerato, L, Dziubinska-Kühn, Gins, W, Gustafsson, F. P, Javaji, A, Jolivet, R. B, Kanellakopoulos, A, Karg, B, Kocman, M. Kempka V, Kozak, M, Kulesz, K, Flores, M. Madurga, Neyens, G, Plavec, R. Pietrzyk J, Pomorski, M, Skrzypczak, A, Wagenknecht, P, Wienholtz, F, Xu, J. Wolak Z, Zakoucky, D, Kowalska, M
• Format: Journal Article
• Language: English
• Published: 06.04.2020
• Subjects: Physics - Chemical Physics; Physics - Nuclear Experiment
• DOI: 10.48550/arxiv.2004.02820

Phys. Rev. X 10, 041061 (2020) We determine for the first time the magnetic dipole moment of a short-lived nucleus with part-per-million (ppm) accuracy. To achieve this two orders of magnitude improvement over previous studies, we implement a number of innovations into our $\beta$-detected Nuclear Magnetic Resonance ($\beta$-NMR) setup at ISOLDE/CERN. Using liquid samples as hosts we obtain narrow, sub-kHz linewidth, resonances, while a simultaneous in-situ $^1$H NMR measurement allows us to calibrate and stabilize the magnetic field to ppm precision, thus eliminating the need for additional $\beta$-NMR reference measurements. Furthermore, we use ab initio calculations of NMR shielding constants to improve the accuracy of the reference magnetic moment, thus removing a large systematic error. We demonstrate the potential of this combined approach with the 1.1 s half-life radioactive nucleus $^{26}$Na, which is relevant for biochemical studies. Our technique can be readily extended to other isotopic chains, providing accurate magnetic moments for many short-lived nuclei. Furthermore, we discuss how our approach can open the path towards a wide range of applications of the ultra-sensitive $\beta$-NMR in physics, chemistry, and biology.