Gas Phase Polymerization of Ethylene with Supported Titanium-Nickel Catalysts

O6; A new ditransition-metal catalyst system TiCl4-NiCl2/MgCl2-SiO2/AlR3 was prepared.Gas phase polymerization of ethylene with the catalysts has been studied.The kinetic curves of gas phase polymerization showed a decline.The catalystic efficiency and polymerization reaction rates have a optimum va...

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Bibliographic Details
Published in中国化学快报(英文版) Vol. 11; no. 1; pp. 85 - 86
Main Authors Jin Min HU, Hai Hua WANG, Jiang Li WU, Qi Xing ZHANG
Format Journal Article
LanguageEnglish
Published Institute of Polymer Science, Zhongshan University, Guangzhou 510275 2000
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Summary:O6; A new ditransition-metal catalyst system TiCl4-NiCl2/MgCl2-SiO2/AlR3 was prepared.Gas phase polymerization of ethylene with the catalysts has been studied.The kinetic curves of gas phase polymerization showed a decline.The catalystic efficiency and polymerization reaction rates have a optimum value when Ni content of the catalysts was 12.5%(mol).The products obtained are branched polyethylene.
ISSN:1001-8417