Chiral lipophilic ligands .5. Enantioselective ester cleavage of alpha-amino esters by Cu(II) complexes of chiral diamino alcohols in aqueous surfactants solutions

• Published in: Tetrahedron Vol. 53; no. 1; pp. 357 - 368
• Main Authors: Cleij, MC, Mancin, F, Scrimin, P, Tecilla, P, Tonellato, U
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier 06.01.1997
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; METALLOMICELLES; PEPTIDES; MODELS; MEMBRANE; HYDROLYSIS; MICELLES; METAL-ION COMPLEXES; PARA-NITROPHENYL PICOLINATE; CATALYSTS; ACID ESTERS

A series of lipophilic ligands, 1-3, featuring an 1,2-ethylendiamino moiety as chelating subunit, one (1, 3) or two (2) chiral carbons, and an hydroxy function (except for 3) in the proximity of the coordination center, have been synthesized. Their Cu(II) complexes have been investigated as catalyst...