[(Epy)2][MnBr2I2]配合物的合成、晶体结构及发光性能

O614.7+11; 室温下,以N-乙基吡啶碘盐(Epy)I和四水溴化锰(MnBr2·4H2 O)为原料合成了一种零维发光材料[(Epy)2][MnBr2 I2].对该配合物进行元素含量分析、红外光谱、单晶X射线衍射、粉末X射线衍射、紫外可见吸收光谱、光致发光光谱及X射线激发发射光谱等测试.单晶X射线衍射结果表明:配合物为单斜晶系,C2/c空间群,中心离子Mn(Ⅱ)为四面体构型,晶胞参数为a=2.8255(6)nm,b=0.83971(17)nm,c=1.8360(4)nm.在332 nm紫外光激发下,配合物发出528 nm的绿光,对应于四面体Mn(Ⅱ)配合物的4 T1(G)→6 A1特征辐射...

Full description

Saved in:
Bibliographic Details
Published in人工晶体学报 Vol. 50; no. 2; pp. 345 - 352
Main Authors 杨晨乐, 李凌燕, 李嫚, 沈轶明, 潘尚可, 潘建国
Format Journal Article
LanguageChinese
Published 浙江省光电探测材料及器件重点实验室,宁波 315211 01.02.2021
宁波大学材料科学与化学工程学院,宁波 315211%宁波大学材料科学与化学工程学院,宁波 315211
Subjects
锰(Ⅱ)配合物
发光性能
晶体结构
离子液体
Online AccessGet full text

Cover

Abstract O614.7+11; 室温下,以N-乙基吡啶碘盐(Epy)I和四水溴化锰(MnBr2·4H2 O)为原料合成了一种零维发光材料[(Epy)2][MnBr2 I2].对该配合物进行元素含量分析、红外光谱、单晶X射线衍射、粉末X射线衍射、紫外可见吸收光谱、光致发光光谱及X射线激发发射光谱等测试.单晶X射线衍射结果表明:配合物为单斜晶系,C2/c空间群,中心离子Mn(Ⅱ)为四面体构型,晶胞参数为a=2.8255(6)nm,b=0.83971(17)nm,c=1.8360(4)nm.在332 nm紫外光激发下,配合物发出528 nm的绿光,对应于四面体Mn(Ⅱ)配合物的4 T1(G)→6 A1特征辐射跃迁,荧光寿命为58.85μs,荧光量子产率为58.29％.X射线激发光谱表明配合物发光强度较高,具有X射线荧光性能.
AbstractList O614.7+11; 室温下,以N-乙基吡啶碘盐(Epy)I和四水溴化锰(MnBr2·4H2 O)为原料合成了一种零维发光材料[(Epy)2][MnBr2 I2].对该配合物进行元素含量分析、红外光谱、单晶X射线衍射、粉末X射线衍射、紫外可见吸收光谱、光致发光光谱及X射线激发发射光谱等测试.单晶X射线衍射结果表明:配合物为单斜晶系,C2/c空间群,中心离子Mn(Ⅱ)为四面体构型,晶胞参数为a=2.8255(6)nm,b=0.83971(17)nm,c=1.8360(4)nm.在332 nm紫外光激发下,配合物发出528 nm的绿光,对应于四面体Mn(Ⅱ)配合物的4 T1(G)→6 A1特征辐射跃迁,荧光寿命为58.85μs,荧光量子产率为58.29％.X射线激发光谱表明配合物发光强度较高,具有X射线荧光性能.
Author 杨晨乐
李嫚
潘尚可
李凌燕
沈轶明
潘建国
AuthorAffiliation 宁波大学材料科学与化学工程学院,宁波 315211%宁波大学材料科学与化学工程学院,宁波 315211;浙江省光电探测材料及器件重点实验室,宁波 315211
AuthorAffiliation_xml – name: 宁波大学材料科学与化学工程学院,宁波 315211%宁波大学材料科学与化学工程学院,宁波 315211;浙江省光电探测材料及器件重点实验室,宁波 315211
Author_FL PAN Shangke
LI Lingyan
LI Man
PAN Jianguo
SHEN Yiming
YANG Chenyue
Author_FL_xml – sequence: 1
  fullname: YANG Chenyue
– sequence: 2
  fullname: LI Lingyan
– sequence: 3
  fullname: LI Man
– sequence: 4
  fullname: SHEN Yiming
– sequence: 5
  fullname: PAN Shangke
– sequence: 6
  fullname: PAN Jianguo
Author_xml – sequence: 1
  fullname: 杨晨乐
– sequence: 2
  fullname: 李凌燕
– sequence: 3
  fullname: 李嫚
– sequence: 4
  fullname: 沈轶明
– sequence: 5
  fullname: 潘尚可
– sequence: 6
  fullname: 潘建国
BookMark eNrjYmDJy89LZWHgNDQwMNC1tDCN4GDgLS7OTAJyLcyMDCwsOBkcozVcCyo1jWKjffOciow8jWJftvY-ndDxvHPl81ktQMazjgmPGxqfzdz2ZO_k57snP5vX8rS_62n_xKetnc8alr9o3svDwJqWmFOcyguluRlC3VxDnD10ffzdPZ0dfXSLDQ1MLHTNLI1SjE3M09LMElOTUwyTU81MDcwSDS3MjYyBImmWJmaWKWnmJuYWZuZGBgbGlkmJaWYpSclpqUkmhiapqSbG3AyaEHPLE_PSEvPS47PyS4vygDbGF6VnlVQkWVoYGRgZGhgZGFoYAwDE_Vdc
ClassificationCodes O614.7+11
ContentType Journal Article
Copyright Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
Copyright_xml – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
DBID 2B.
4A8
92I
93N
PSX
TCJ
DatabaseName Wanfang Data Journals - Hong Kong
WANFANG Data Centre
Wanfang Data Journals
万方数据期刊 - 香港版
China Online Journals (COJ)
China Online Journals (COJ)
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
DocumentTitle_FL Synthesis,Crystal Structure and Luminescence Properties of [(Epy)2 ][MnBr2 I2 ]Complex
EndPage 352
ExternalDocumentID rgjtxb98202102018
GrantInformation_xml – fundername: 国家自然科学基金
  funderid: (61775108,61875096)
GroupedDBID -01
2B.
2C.
4A8
5XA
5XB
5XC
92E
92I
93N
ABDBF
ABJNI
ACGFS
ALMA_UNASSIGNED_HOLDINGS
CCEZO
CCVFK
CW9
PSX
TCJ
TGP
U1G
U5K
U5L
ID FETCH-LOGICAL-s1048-692d347ff6aecd1ce6506a187236aef9469df74786720039baf6dbcfeb414ee43
ISSN 1000-985X
IngestDate Wed Nov 06 04:33:47 EST 2024
IsPeerReviewed true
IsScholarly true
Issue 2
Keywords 锰(Ⅱ)配合物
发光性能
晶体结构
离子液体
Language Chinese
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-s1048-692d347ff6aecd1ce6506a187236aef9469df74786720039baf6dbcfeb414ee43
PageCount 8
ParticipantIDs wanfang_journals_rgjtxb98202102018
PublicationCentury 2000
PublicationDate 2021-02-01
PublicationDateYYYYMMDD 2021-02-01
PublicationDate_xml – month: 02
  year: 2021
  text: 2021-02-01
  day: 01
PublicationDecade 2020
PublicationTitle 人工晶体学报
PublicationTitle_FL Journal of Synthetic Crystals
PublicationYear 2021
Publisher 浙江省光电探测材料及器件重点实验室,宁波 315211
宁波大学材料科学与化学工程学院,宁波 315211%宁波大学材料科学与化学工程学院,宁波 315211
Publisher_xml – name: 浙江省光电探测材料及器件重点实验室,宁波 315211
– name: 宁波大学材料科学与化学工程学院,宁波 315211%宁波大学材料科学与化学工程学院,宁波 315211
SSID ssib000862088
ssib023167813
ssib051369607
ssj0000547349
Score 2.2995033
Snippet O614.7+11; 室温下,以N-乙基吡啶碘盐(Epy)I和四水溴化锰(MnBr2·4H2 O)为原料合成了一种零维发光材料[(Epy)2][MnBr2...
SourceID wanfang
SourceType Aggregation Database
StartPage 345
Title [(Epy)2][MnBr2I2]配合物的合成、晶体结构及发光性能
URI https://d.wanfangdata.com.cn/periodical/rgjtxb98202102018
Volume 50
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1NaxQxNHTXix7ET_ymiAFFVnaSTCY5Jt1ZqlBPLRRKKTOzMxUPq7RbkJ4qttAK0kpPevAq_gEv0l-ju6v_wvcy6e649lCFIbzJe3l5H5PJy5C8IeRe2uSAKmB1gkd8RMpUI0mkaBRpKjVG6FGCnwbmnsrZBfFkMVycqm1Vdi1t9NJH2eaJ50r-x6tQB37FU7L_4NkRU6gAGPwLJXgYylP5mIYWAsT4JRhKMxq24H6ua9fYY3cTa6pCqgAIqW5SpWgcUaWp0QhoQ5WooCSWAMccNz-oAGu0plbSWFDboppjK2sdAKjYN1dtqowHdOCAEHtBhk1qIhorqjhwqIbBjqfBC-htRE14UnchNS1qpGNlgOb44XC0gFG-EQLQSFPdnCBRsRMI1J5xyoPak1xKEgN6mSrGMmcVhbJYJ4IGPeLqRxIWHO-r9o-1axeiRAgEVLedoWecNUd2gRqBZKhVTA3zrZT1AqEPAHCaVe07VtQ6ibTTq-X0Yqg9qhGjYwBljFPZ1RgB48jDpV8th34fcgyqgsqshMf_tQoXq9NWma_XD09WmYN4mZ_ThzO8TBA8kVR8bfV571WqFXNL_magaqQGvdbJGWNbtv3Hgrc5TmjHMG-CGgeAYYC_g_QfEMps-iLibs05ktmdhusWSXe1ErjNXyDn_Ypr2pTD5yKZ2nx2iZyr5OG8TMzSfRhED9jykh8-y7923vUPdod7X4YftwEY7B5833o9-PD1x9Hh8Nvh4NN2f_9tf_99f2dvsPX555ujK2ShHc_PzDb8v0Ua6wFMWg14EXW4iIpCJnnWCbIcVioyCVTEONQUWkjdKfDfEjLC7Zs6TQrZSbMiT0Ug8lzwq6TefdHNr5Fpjin-OkkqswiQsqMgZAe2TEF0XTCdXSd3vQFW_LtjfeUv-984DdFNcnb8cN8i9d7aRn4bYuJeesc77jdAs4Hc
link.rule.ids 315,783,787
linkProvider EBSCOhost
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%5B%28Epy%292%5D%5BMnBr2I2%5D%E9%85%8D%E5%90%88%E7%89%A9%E7%9A%84%E5%90%88%E6%88%90%E3%80%81%E6%99%B6%E4%BD%93%E7%BB%93%E6%9E%84%E5%8F%8A%E5%8F%91%E5%85%89%E6%80%A7%E8%83%BD&rft.jtitle=%E4%BA%BA%E5%B7%A5%E6%99%B6%E4%BD%93%E5%AD%A6%E6%8A%A5&rft.au=%E6%9D%A8%E6%99%A8%E4%B9%90&rft.au=%E6%9D%8E%E5%87%8C%E7%87%95&rft.au=%E6%9D%8E%E5%AB%9A&rft.au=%E6%B2%88%E8%BD%B6%E6%98%8E&rft.date=2021-02-01&rft.pub=%E6%B5%99%E6%B1%9F%E7%9C%81%E5%85%89%E7%94%B5%E6%8E%A2%E6%B5%8B%E6%9D%90%E6%96%99%E5%8F%8A%E5%99%A8%E4%BB%B6%E9%87%8D%E7%82%B9%E5%AE%9E%E9%AA%8C%E5%AE%A4%2C%E5%AE%81%E6%B3%A2+315211&rft.issn=1000-985X&rft.volume=50&rft.issue=2&rft.spage=345&rft.epage=352&rft.externalDocID=rgjtxb98202102018
thumbnail_s http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Frgjtxb98%2Frgjtxb98.jpg