有机胺改性树脂基球形活性炭对二氧化碳的吸附行为

TQ09; 以球形结构的固废离子交换树脂为原料,经CO2活化、酸洗处理制得具有较高比表面积和较大中孔孔容的树脂基球形活性炭(HRSAC),然后在其表面负载聚乙烯亚胺(PEI)制得吸附材料PEI-HRSAC.系统考察了 PEI负载量和吸附温度对CO2吸附性能的影响,结果表明,在活化温度为950℃、活化时间为1 h的最佳活化工艺条件下,所制得的树脂基球形活性炭经酸洗处理后其比表面积为1 365 m2/g,中孔孔容为2.04 cm3/g,中孔孔径主要分布在10～40 nm;PEI-HRSAC吸附材料对CO2的吸附性能随吸附温度和PEI负载量的升高先增大后减小;当PEI负载量为65％、吸附温度为75...

Full description

Saved in:
Bibliographic Details
Published in华东理工大学学报（自然科学版） Vol. 50; no. 2; pp. 192 - 198
Main Authors 胡经纬, 苏静雯, 刘思彤, 李诗琪, 陈纪莹, 詹亮
Format Journal Article
LanguageChinese
Published 华东理工大学化工学院,化学工程联合国家重点实验室,上海 200237 01.05.2024
Subjects
球形活性炭
聚乙烯亚胺
离子交换树脂
比表面积
specific surface area
ion exchange resin
polyethyleneimine
CO2吸附
CO2 adsorption
spherical activated carbon
Online AccessGet full text

Cover

Abstract TQ09; 以球形结构的固废离子交换树脂为原料,经CO2活化、酸洗处理制得具有较高比表面积和较大中孔孔容的树脂基球形活性炭(HRSAC),然后在其表面负载聚乙烯亚胺(PEI)制得吸附材料PEI-HRSAC.系统考察了 PEI负载量和吸附温度对CO2吸附性能的影响,结果表明,在活化温度为950℃、活化时间为1 h的最佳活化工艺条件下,所制得的树脂基球形活性炭经酸洗处理后其比表面积为1 365 m2/g,中孔孔容为2.04 cm3/g,中孔孔径主要分布在10～40 nm;PEI-HRSAC吸附材料对CO2的吸附性能随吸附温度和PEI负载量的升高先增大后减小;当PEI负载量为65％、吸附温度为75 ℃时,PEI-HRSAC吸附材料对CO2的吸附量最高,约为4.09mmol/g,在经过4次循环吸/脱附后吸附量仍保持在较高水平(3.66 mmol/g).
AbstractList TQ09; 以球形结构的固废离子交换树脂为原料,经CO2活化、酸洗处理制得具有较高比表面积和较大中孔孔容的树脂基球形活性炭(HRSAC),然后在其表面负载聚乙烯亚胺(PEI)制得吸附材料PEI-HRSAC.系统考察了 PEI负载量和吸附温度对CO2吸附性能的影响,结果表明,在活化温度为950℃、活化时间为1 h的最佳活化工艺条件下,所制得的树脂基球形活性炭经酸洗处理后其比表面积为1 365 m2/g,中孔孔容为2.04 cm3/g,中孔孔径主要分布在10～40 nm;PEI-HRSAC吸附材料对CO2的吸附性能随吸附温度和PEI负载量的升高先增大后减小;当PEI负载量为65％、吸附温度为75 ℃时,PEI-HRSAC吸附材料对CO2的吸附量最高,约为4.09mmol/g,在经过4次循环吸/脱附后吸附量仍保持在较高水平(3.66 mmol/g).
Abstract_FL Resin-based spherical activated carbon(RSAC)with high specific surface area and large mesopore volume(HRSAC)was prepared from spherical solid waste ion exchange resin by CO2 activation and acid treatment,and HRSAC supported polyethyleneimine(PEI-HRSAC)adsorption materials were prepared.The effects of PEI loading and adsorption temperature on CO2 adsorption performance were systematically investigated.The results indicate that the optimal activation conditions are the activation temperature of 950 ℃ and activation time of 1 h.Subsequently,the as-prepared RSAC is treated with hydrochloric acid,and the obtained supported HRSAC has a specific surface area of 1 365 m2/g.The mesopore volume of 2.04 cm3/g,and the mesopore diameter is mainly distributed in the range of 10-40 nm.The CO2 adsorption performance of PEI-HRSAC adsorption materials increases firstly and then decreases with the increasing of adsorption temperature and PEI loading,respectively.When the PEI loading is 65％and the adsorption temperature is 75 ℃,the CO2 adsorption capacity of the obtained adsorption materials reaches the maximum value of 4.09 mmol/g,and remains at a high level(3.66 mmol/g)after 4 cycles of adsorption and desorption.
Author 苏静雯
李诗琪
陈纪莹
詹亮
胡经纬
刘思彤
AuthorAffiliation 华东理工大学化工学院,化学工程联合国家重点实验室,上海 200237
AuthorAffiliation_xml – name: 华东理工大学化工学院,化学工程联合国家重点实验室,上海 200237
Author_FL LI Shiqi
CHEN Jiying
SU Jingwen
ZHAN Liang
HU Jingwei
LIU Sitong
Author_FL_xml – sequence: 1
  fullname: HU Jingwei
– sequence: 2
  fullname: SU Jingwen
– sequence: 3
  fullname: LIU Sitong
– sequence: 4
  fullname: LI Shiqi
– sequence: 5
  fullname: CHEN Jiying
– sequence: 6
  fullname: ZHAN Liang
Author_xml – sequence: 1
  fullname: 胡经纬
– sequence: 2
  fullname: 苏静雯
– sequence: 3
  fullname: 刘思彤
– sequence: 4
  fullname: 李诗琪
– sequence: 5
  fullname: 陈纪莹
– sequence: 6
  fullname: 詹亮
BookMark eNo9j7tKw1Acxs9QwVr7GA4Oif9zy2WUUi9QcNG5nOTk1NaSgkHsKG0WIUMFEZSC2qWTKOjQRnyb5iS-hQHF6YMfH99lA1XCQRggtIXBxAxTvtMz_fCsa2IAy6DggEmAUKBQAlxB1X--jupR1PUACOEOtnAVNfX0Wk_TYpzq26W-muunmyIeZY9pPhlnXzP98VnCfPSSvS5XaaLf5llyl8_e84c4myy-7-PiOVkt0k20pkQ_Cup_WkMne83jxoHROto_bOy2jAgD44bkBPuu7UMARHHX9y0LJBU2OJhJIT0PM3AV40oyG0qj59qBKHcz5bgOcRStoe3f3EsRKhF22r3BxXlYNrZPZb8jh0OvPM6AAHD6A4TBanQ
ClassificationCodes TQ09
ContentType Journal Article
Copyright Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
Copyright_xml – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
DBID 2B.
4A8
92I
93N
PSX
TCJ
DOI 10.14135/j.cnki.1006-3080.20230301001
DatabaseName Wanfang Data Journals - Hong Kong
WANFANG Data Centre
Wanfang Data Journals
万方数据期刊 - 香港版
China Online Journals (COJ)
China Online Journals (COJ)
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
DocumentTitle_FL Adsorption Behavior of Carbon Dioxide on Organic Amine Modified Resin-Based Spherical Activated Carbon
EndPage 198
ExternalDocumentID hdlgdxxb202402005
GrantInformation_xml – fundername: (国家自然科学基金); (国家自然科学基金); (国家自然科学基金); (国家自然科学基金); (上海市自然科学基金)
  funderid: (国家自然科学基金); (国家自然科学基金); (国家自然科学基金); (国家自然科学基金); (上海市自然科学基金)
GroupedDBID -02
2B.
4A8
92I
93N
ALMA_UNASSIGNED_HOLDINGS
CCEZO
CDRFL
P2P
PSX
TCJ
U1G
U5L
UY8
ID FETCH-LOGICAL-s1045-d521c97c0e02f59cc660d3a70814dadbb1409f45fd470c97b97ea3084f89828f3
ISSN 1006-3080
IngestDate Thu May 29 03:59:03 EDT 2025
IsPeerReviewed true
IsScholarly true
Issue 2
Keywords 球形活性炭
聚乙烯亚胺
离子交换树脂
比表面积
specific surface area
ion exchange resin
polyethyleneimine
CO2吸附
CO2 adsorption
spherical activated carbon
Language Chinese
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-s1045-d521c97c0e02f59cc660d3a70814dadbb1409f45fd470c97b97ea3084f89828f3
PageCount 7
ParticipantIDs wanfang_journals_hdlgdxxb202402005
PublicationCentury 2000
PublicationDate 2024-05-01
PublicationDateYYYYMMDD 2024-05-01
PublicationDate_xml – month: 05
  year: 2024
  text: 2024-05-01
  day: 01
PublicationDecade 2020
PublicationTitle 华东理工大学学报（自然科学版）
PublicationTitle_FL Journal of East China University of Science and Technology(Natural Science Edition)
PublicationYear 2024
Publisher 华东理工大学化工学院,化学工程联合国家重点实验室,上海 200237
Publisher_xml – name: 华东理工大学化工学院,化学工程联合国家重点实验室,上海 200237
SSID ssib002258161
ssib001104923
ssib057620135
ssib035757162
ssib036434644
ssib006703735
ssib000947709
ssib006595864
ssib051370438
ssib023167207
ssib001050798
ssj0039901
Score 2.3750145
Snippet TQ09; 以球形结构的固废离子交换树脂为原料,经CO2活化、酸洗处理制得具有较高比表面积和较大中孔孔容的树脂基球形活性炭(HRSAC),然后在其表面负载聚乙烯亚胺(PEI)制得吸附材料PEI-HRSAC.系统考察了 PEI负载量和吸附温度对CO2吸附性能的影响,结果表明,在活化温度为950℃、活化时间为1...
SourceID wanfang
SourceType Aggregation Database
StartPage 192
Title 有机胺改性树脂基球形活性炭对二氧化碳的吸附行为
URI https://d.wanfangdata.com.cn/periodical/hdlgdxxb202402005
Volume 50
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1NaxQxdChbED2In_hNEXPcOpNJJskxsztLEevFFnoruzM7rV8r2BZKT9L2IvRQQQSloPbSkyjooV3x33R367_wvSS7O0tFqpch8_Je8r5mkpeZvHjeHREEYRbyqKwauSgzUc_KMs3Ssp9zLvOMB7nZLjb9IJqaZffm-NxY6Vnhr6WV5cZkuvbHfSX_Y1WAgV1xl-w_WHbQKACgDPaFK1gYrieyMUkioipEKleINUkkkaEpAISR2FRJn2iBBe0TFRgcmEJSknCiagZZEOUjIUDiKtEUkWMgjwvkAkl0FXF0zbTMkFZWDLLF4XirIkSGRuLQtKyxO-zLJ7EkiSJKGYgkOjDkDOFuxeBxXzRoqkpk4mpBOsdkZJiE9rnhhLl-gTEdFQrAtjY4wCqoSBqpgcoIC73HlklhFDKgEqhMRLZUg1USp1fgF1BAK7JmCtBDZQTF1oCEVRQSCzEoa4jCsXElnVZVta9wNkSJEIxyS1SzEk5urYsLNJQNf4c0j9T_68sZrIhjq4ydwIq0MoI2IHT4cDWCo_gB-py1NCqRo_ix9ZjEaFyhDYBP60zoQ6ZKJVilrTMZCPBJ-54hjTfH2CNmwKQ2f48bSn3zV6U9p6s_1tokw-6dQgsDZ2BPRHRzsMCeTH5seIcZFzfje9p68mhy0MMkxUgahirf6X00g_pi9nQhW11toHF8m_F4nEJUSUveuK5O339YiDeYGMln6EO4VFiPgLkyK643wGAog8LGcEzOWTzuIILxVAzjEYppJ-hwvSWEWKmfwc3cQ3jAouF8mwehwC_1g3uYuUDINojvQ_yobX7ncIo45ZG-mu7-TUlmh2Irr7cWCpPpmXPeWRcFT2j7Sjvvja0tXvDOFHKjXvSS7s6r7k77aKPdfXPQfbnX_fj6aHO986Hd297o_Nztfv8BwN76586Xg8P2VvfrXmfrbW_3W-_9Zmd7_9e7zaNPW4f77UvebC2ZqUyV3Zkv5SXQLS9nEE6kSqR-06c5V2kaRX4W1gVELiyrZ40GJujLGc8zJnxAbCjRrIN4LJdKUpmHl71S63mrecWbCCIpAvP5MqtjWkTZFIzSwE_TPIzSprjq3XZKmHfv9KX5Y65y7SRI173Twwf_hldafrHSvAmxynLjlvOw3znl5TA
linkProvider EBSCOhost
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E6%9C%89%E6%9C%BA%E8%83%BA%E6%94%B9%E6%80%A7%E6%A0%91%E8%84%82%E5%9F%BA%E7%90%83%E5%BD%A2%E6%B4%BB%E6%80%A7%E7%82%AD%E5%AF%B9%E4%BA%8C%E6%B0%A7%E5%8C%96%E7%A2%B3%E7%9A%84%E5%90%B8%E9%99%84%E8%A1%8C%E4%B8%BA&rft.jtitle=%E5%8D%8E%E4%B8%9C%E7%90%86%E5%B7%A5%E5%A4%A7%E5%AD%A6%E5%AD%A6%E6%8A%A5%EF%BC%88%E8%87%AA%E7%84%B6%E7%A7%91%E5%AD%A6%E7%89%88%EF%BC%89&rft.au=%E8%83%A1%E7%BB%8F%E7%BA%AC&rft.au=%E8%8B%8F%E9%9D%99%E9%9B%AF&rft.au=%E5%88%98%E6%80%9D%E5%BD%A4&rft.au=%E6%9D%8E%E8%AF%97%E7%90%AA&rft.date=2024-05-01&rft.pub=%E5%8D%8E%E4%B8%9C%E7%90%86%E5%B7%A5%E5%A4%A7%E5%AD%A6%E5%8C%96%E5%B7%A5%E5%AD%A6%E9%99%A2%2C%E5%8C%96%E5%AD%A6%E5%B7%A5%E7%A8%8B%E8%81%94%E5%90%88%E5%9B%BD%E5%AE%B6%E9%87%8D%E7%82%B9%E5%AE%9E%E9%AA%8C%E5%AE%A4%2C%E4%B8%8A%E6%B5%B7+200237&rft.issn=1006-3080&rft.volume=50&rft.issue=2&rft.spage=192&rft.epage=198&rft_id=info:doi/10.14135%2Fj.cnki.1006-3080.20230301001&rft.externalDocID=hdlgdxxb202402005
thumbnail_s http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fhdlgdxxb%2Fhdlgdxxb.jpg