红柳林煤温和液化性能研究

TQ529.1; 在相对温和条件下,考察了反应温度、氢气压力、溶剂供氢性能和催化剂对红柳林煤液化性能的影响.结果表明:在370～390℃ 范围内,温度升高的主要作用是促进煤的大分子结构解聚;在390～430℃ 范围内,温度升高的主要作用是促进重质产物二次裂解.此外,在Fe催化剂中加入碱性催化剂之后,Fe催化剂与碱性催化剂之间产生了协同效应,使得煤中大量含氧官能团(如醚键、羰基)水解及煤中大分子结构解聚,因而煤转化率和油产率增加,氢气消耗量增加,水产率降低....

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Published in华东理工大学学报（自然科学版） Vol. 47; no. 2; pp. 163 - 169
Main Authors 王海奇, 黄胜, 吴诗勇, 钱嘉澍, 吴幼青, 高晋生
Format Journal Article
LanguageChinese
Published 华东理工大学资源与环境工程学院能源化工系,上海 200237 30.04.2021
Subjects
供氢溶剂
催化剂
温和液化
红柳林煤
Online AccessGet full text
ISSN1006-3080
DOI10.14135/j.cnki.1006-3080.20191208001

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Abstract TQ529.1; 在相对温和条件下,考察了反应温度、氢气压力、溶剂供氢性能和催化剂对红柳林煤液化性能的影响.结果表明:在370～390℃ 范围内,温度升高的主要作用是促进煤的大分子结构解聚;在390～430℃ 范围内,温度升高的主要作用是促进重质产物二次裂解.此外,在Fe催化剂中加入碱性催化剂之后,Fe催化剂与碱性催化剂之间产生了协同效应,使得煤中大量含氧官能团(如醚键、羰基)水解及煤中大分子结构解聚,因而煤转化率和油产率增加,氢气消耗量增加,水产率降低.
AbstractList TQ529.1; 在相对温和条件下,考察了反应温度、氢气压力、溶剂供氢性能和催化剂对红柳林煤液化性能的影响.结果表明:在370～390℃ 范围内,温度升高的主要作用是促进煤的大分子结构解聚;在390～430℃ 范围内,温度升高的主要作用是促进重质产物二次裂解.此外,在Fe催化剂中加入碱性催化剂之后,Fe催化剂与碱性催化剂之间产生了协同效应,使得煤中大量含氧官能团(如醚键、羰基)水解及煤中大分子结构解聚,因而煤转化率和油产率增加,氢气消耗量增加,水产率降低.
Author 吴诗勇
吴幼青
黄胜
王海奇
钱嘉澍
高晋生
AuthorAffiliation 华东理工大学资源与环境工程学院能源化工系,上海 200237
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WU Shiyong
WU Youqing
GAO Jinsheng
QIAN Jiashu
HUANG Sheng
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Keywords 供氢溶剂
催化剂
温和液化
红柳林煤
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Snippet TQ529.1; 在相对温和条件下,考察了反应温度、氢气压力、溶剂供氢性能和催化剂对红柳林煤液化性能的影响.结果表明:在370～390℃ 范围内,温度升高的主要作用是促进煤的大分子结构解聚;在390～430℃...
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Title 红柳林煤温和液化性能研究
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Volume 47
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