草酸配体修饰的锆取代型硅钨-氧簇合物的合成、结构和电化学性质研究
O611; 通过水热反应,成功合成了一个草酸配体修饰的四核锆取代的夹心型硅钨-氧簇合物H12 Na2[Zr4(μ3-O)2(μ2-OH)2(Ox)2(α-SiW10O37)2]·22H2O(Ox=oxalic acid).该夹心型硅钨-氧簇是由两个{α-SiW10O37}簇块通过一个{Zr4(μ3-O)2(μ2-OH)2(Ox)2}簇连接构成的.通过X-射线单晶衍射、IR、TG以及元素分析对该簇合物进行表征.晶体结构分析表明:该簇合物结晶于单斜晶系,P21/c空间群,a=2.1322(6)nm,b=1.2716(4)nm,c=2.2231(7)nm,β=110.933(4)°,V=5.6299...
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| Published in | 人工晶体学报 Vol. 50; no. 5; pp. 884 - 888 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | Chinese |
| Published |
渤海大学化学与材料工程学院,辽宁省全谱太阳能电池转光材料专业技术创新中心,锦州 121013
01.05.2021
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-985X |
| DOI | 10.3969/j.issn.1000-985X.2021.05.014 |
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| Abstract | O611; 通过水热反应,成功合成了一个草酸配体修饰的四核锆取代的夹心型硅钨-氧簇合物H12 Na2[Zr4(μ3-O)2(μ2-OH)2(Ox)2(α-SiW10O37)2]·22H2O(Ox=oxalic acid).该夹心型硅钨-氧簇是由两个{α-SiW10O37}簇块通过一个{Zr4(μ3-O)2(μ2-OH)2(Ox)2}簇连接构成的.通过X-射线单晶衍射、IR、TG以及元素分析对该簇合物进行表征.晶体结构分析表明:该簇合物结晶于单斜晶系,P21/c空间群,a=2.1322(6)nm,b=1.2716(4)nm,c=2.2231(7)nm,β=110.933(4)°,V=5.6299(3)nm3,Z=2,R1=0.0615,wR2=0.1644.电化学和电催化性质研究表明标题簇合物对NO2-的还原有很好的电催化效果. |
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| AbstractList | O611; 通过水热反应,成功合成了一个草酸配体修饰的四核锆取代的夹心型硅钨-氧簇合物H12 Na2[Zr4(μ3-O)2(μ2-OH)2(Ox)2(α-SiW10O37)2]·22H2O(Ox=oxalic acid).该夹心型硅钨-氧簇是由两个{α-SiW10O37}簇块通过一个{Zr4(μ3-O)2(μ2-OH)2(Ox)2}簇连接构成的.通过X-射线单晶衍射、IR、TG以及元素分析对该簇合物进行表征.晶体结构分析表明:该簇合物结晶于单斜晶系,P21/c空间群,a=2.1322(6)nm,b=1.2716(4)nm,c=2.2231(7)nm,β=110.933(4)°,V=5.6299(3)nm3,Z=2,R1=0.0615,wR2=0.1644.电化学和电催化性质研究表明标题簇合物对NO2-的还原有很好的电催化效果. |
| Author | 李晓慧 张众 王梓兰 杨琳 王静怡 |
| AuthorAffiliation | 渤海大学化学与材料工程学院,辽宁省全谱太阳能电池转光材料专业技术创新中心,锦州 121013 |
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| Author_FL | WANG Zilan WANG Jingyi LI Xiaohui ZHANG Zhong YANG Lin |
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| DocumentTitle_FL | Synthesis, Crystal Structure, and Electrochemical Properties of a Ox-Functionalized Zirconium(Ⅳ) Substituted Tungsten-Oxo Cluster |
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| Keywords | 电催化性质 水热合成 晶体结构 钨-氧簇合物 电化学 草酸 |
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| Publisher | 渤海大学化学与材料工程学院,辽宁省全谱太阳能电池转光材料专业技术创新中心,锦州 121013 |
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| Snippet | O611; 通过水热反应,成功合成了一个草酸配体修饰的四核锆取代的夹心型硅钨-氧簇合物H12 Na2[Zr4(μ3-O)2(μ2-OH)2(Ox)2(α-SiW10O37)2]·22H2O(Ox=oxalic... |
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| Title | 草酸配体修饰的锆取代型硅钨-氧簇合物的合成、结构和电化学性质研究 |
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