High‐temperature dielectric properties and impedance spectroscopy of PbHf1−x Snx O3 ceramics

• Published in: IET Nanodielectrics Vol. 3; no. 4; pp. 131 - 137
• Main Authors: Liu, Zhi‐Gang, Ge, Peng‐Zu, Tang, Hui, Tang, Xin‐Gui, Zeng, Si‐Ming, Jiang, Yan‐Ping, Tang, Zhen‐Hua, Liu, Qiu‐Xiang
• Format: Journal Article
• Language: English
• Published: Beijing The Institution of Engineering and Technology 01.12.2020; John Wiley & Sons, Inc
• Subjects: activation energy; antiferroelectric materials; Antiferroelectricity; Ceramics; Chemical synthesis; complex impedance plots; Conduction heating; conventional solid‐state reaction method; Dielectric properties; Dielectric relaxation; FE phase; ferroelectric ceramics; ferroelectric phase; ferroelectric transitions; high‐temperature dielectric relaxation; Hopping conduction; Impedance spectroscopy; intermediate antiferroelectric phase; lead compounds; oxygen vacancies; paraelectric phase; PbHf1‐x Snx O3; PE phase; phase transition temperature; Phase transitions; PSH ceramics; Single crystals; Spectrum analysis; Temperature; temperature 20.0 degC to 650.0 degC; Transition temperature; vacancies (crystal); China
• DOI: 10.1049/iet-nde.2020.0030
• ISSN: 2514-3255

PbHf1−x Snx O3 (PSH) ceramics were synthesised by a conventional solid‐state reaction method. Dielectric properties were investigated in the temperature range of 20–650°C. As the Sn4+ content goes up, the phase transition temperatures of an antiferroelectric (AFE1) to another intermediate antiferroelectric (AFE2) phase and AFE2 to the paraelectric (PE) phase decrease gradually. When x ≥0.1 for PSH ceramics, the ferroelectric (FE) phase appears around 225°C, and phase transition temperature from FE phase to PE phase goes up with the increasing concentration of Sn4+. Moreover, high‐temperature dielectric relaxation (HTDR) phenomenon can be seen from all samples. Mechanism of HTDR was discussed from impedance spectroscopy and conductivity for PSH ceramics. It was found that three dielectric responses were observed in complex impedance plots and HTDR was involved with the movement of oxygen vacancies. Activation energy calculated from dielectric data suggested that the HTDR was governed by the hopping conduction process.