Structure of the Au23−xAgx(S‐Adm)15 Nanocluster and Its Application for Photocatalytic Degradation of Organic Pollutants

Ligands play an important role in determining the atomic arrangement within the metal nanoclusters. Here, we report a new nanocluster [Au23−xAgx(S‐Adm)15] protected by bulky adamantanethiol ligands which was obtained through a one‐pot synthesis. The total structure of [Au23−xAgx(S‐Adm)15] comprises...

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Published inAngewandte Chemie Vol. 131; no. 33; pp. 11457 - 11461
Main Authors Liu, Chao, Ren, Xiuqing, Lin, Feng, Fu, Xuemei, Lin, Xinzhang, Li, Tao, Sun, Keju, Huang, Jiahui
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 12.08.2019
Subjects
Catalytic activity
Chemistry
Environmental degradation
Icosahedral phase
Irradiation
Legierungen
Ligands
Light irradiation
Molecular orbitals
Nanocluster
Nanoclusters
Phenols
Photocatalysis
Photodegradation
Photokatalyse
Pollutants
Rhodamine
Spectroscopy
Thiole
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Abstract Ligands play an important role in determining the atomic arrangement within the metal nanoclusters. Here, we report a new nanocluster [Au23−xAgx(S‐Adm)15] protected by bulky adamantanethiol ligands which was obtained through a one‐pot synthesis. The total structure of [Au23−xAgx(S‐Adm)15] comprises an Au13−xAgx icosahedral core, three Au3(SR)4 units, and one AgS3 staple motif in contrast to the 15‐atom bipyramidal core previously seen in [Au23−xAgx(SR)16]. UV/Vis spectroscopy indicates that the HOMO–LUMO gap of [Au23−xAgx(S‐Adm)15] is 1.5 eV. DFT calculations reveal that [Au19Ag4(S‐Adm)15] is the most stable structure among all structural possibilities. Benefitting from Ag doping, [Au23−xAgx(S‐Adm)15] exhibits drastically improved photocatalytic activity for the degradation of rhodamine B (RhB) and phenol under visible‐light irradiation compared to Au23 nanoclusters. Geschützt durch sperrige Liganden: Im Unterschied zum 15‐atomigen bipyramidalen Kern in [Au23−xAgx(SR)16] umfasst die Struktur von [Au23−xAgx(S‐Adm)15] einen ikosaedrischen Au13−xAgx‐Kern, drei Au3(SR)4‐Einheiten und ein klammerartiges AgS3‐Motiv. Dank der Ag‐Dotierung zeigt [Au23−xAgx(S‐Adm)15] eine deutlich bessere photokatalytische Aktivität für den Abbau von Rhodamin B und Phenol unter Bestrahlung mit sichtbarem Licht als Au23‐Nanocluster.
AbstractList Ligands play an important role in determining the atomic arrangement within the metal nanoclusters. Here, we report a new nanocluster [Au23−xAgx(S‐Adm)15] protected by bulky adamantanethiol ligands which was obtained through a one‐pot synthesis. The total structure of [Au23−xAgx(S‐Adm)15] comprises an Au13−xAgx icosahedral core, three Au3(SR)4 units, and one AgS3 staple motif in contrast to the 15‐atom bipyramidal core previously seen in [Au23−xAgx(SR)16]. UV/Vis spectroscopy indicates that the HOMO–LUMO gap of [Au23−xAgx(S‐Adm)15] is 1.5 eV. DFT calculations reveal that [Au19Ag4(S‐Adm)15] is the most stable structure among all structural possibilities. Benefitting from Ag doping, [Au23−xAgx(S‐Adm)15] exhibits drastically improved photocatalytic activity for the degradation of rhodamine B (RhB) and phenol under visible‐light irradiation compared to Au23 nanoclusters. Geschützt durch sperrige Liganden: Im Unterschied zum 15‐atomigen bipyramidalen Kern in [Au23−xAgx(SR)16] umfasst die Struktur von [Au23−xAgx(S‐Adm)15] einen ikosaedrischen Au13−xAgx‐Kern, drei Au3(SR)4‐Einheiten und ein klammerartiges AgS3‐Motiv. Dank der Ag‐Dotierung zeigt [Au23−xAgx(S‐Adm)15] eine deutlich bessere photokatalytische Aktivität für den Abbau von Rhodamin B und Phenol unter Bestrahlung mit sichtbarem Licht als Au23‐Nanocluster.
Ligands play an important role in determining the atomic arrangement within the metal nanoclusters. Here, we report a new nanocluster [Au23−xAgx(S‐Adm)15] protected by bulky adamantanethiol ligands which was obtained through a one‐pot synthesis. The total structure of [Au23−xAgx(S‐Adm)15] comprises an Au13−xAgx icosahedral core, three Au3(SR)4 units, and one AgS3 staple motif in contrast to the 15‐atom bipyramidal core previously seen in [Au23−xAgx(SR)16]. UV/Vis spectroscopy indicates that the HOMO–LUMO gap of [Au23−xAgx(S‐Adm)15] is 1.5 eV. DFT calculations reveal that [Au19Ag4(S‐Adm)15] is the most stable structure among all structural possibilities. Benefitting from Ag doping, [Au23−xAgx(S‐Adm)15] exhibits drastically improved photocatalytic activity for the degradation of rhodamine B (RhB) and phenol under visible‐light irradiation compared to Au23 nanoclusters.
Author Liu, Chao
Lin, Xinzhang
Li, Tao
Sun, Keju
Ren, Xiuqing
Huang, Jiahui
Fu, Xuemei
Lin, Feng
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Snippet Ligands play an important role in determining the atomic arrangement within the metal nanoclusters. Here, we report a new nanocluster [Au23−xAgx(S‐Adm)15]...
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StartPage 11457
SubjectTerms Catalytic activity
Chemistry
Environmental degradation
Icosahedral phase
Irradiation
Legierungen
Ligands
Light irradiation
Molecular orbitals
Nanocluster
Nanoclusters
Phenols
Photocatalysis
Photodegradation
Photokatalyse
Pollutants
Rhodamine
Spectroscopy
Thiole
Title Structure of the Au23−xAgx(S‐Adm)15 Nanocluster and Its Application for Photocatalytic Degradation of Organic Pollutants
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fange.201904612
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Volume 131
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