High-pressure synthesis and study of the crystal and magnetic structure of the distorted SeNiO3 and SeMnO3 perovskites

• Published in: Dalton transactions : an international journal of inorganic chemistry no. 41; p. 4936
• Main Authors: Muñoz, A, Alonso, J A, Martínez-Lope, M J, Falcón, H, García-Hernández, M, Morán, E
• Format: Journal Article
• Language: English
• Published: England 01.01.2006
• DOI: 10.1039/b607905a
• ISSN: 1477-9226

We describe the preparation of SeMO(3) (M = Ni, Mn) under high pressure conditions (3.5 GPa), starting from reactive H(2)SeO(3) and MO mixtures, contained in sealed gold capsules under the reaction conditions 850 degrees C for 1 h. The polycrystalline samples have been studied by neutron powder diffraction (NPD) data and magnetization measurements. SeMO(3) (M = Ni, Mn) are orthorhombically distorted perovskites (space group Pnma). Below T(N) approximately 104 K (M = Ni) and T(N) approximately 53.5 K (M = Mn) these oxides experience an antiferromagnetic ordering, as demonstrated by susceptibility and NPD measurements. The magnetic reflections observed in the neutron patterns can be indexed with a propagation vector k = 0. Both compounds present the same magnetic structure, which is given by the basis vector (0, 0, A(z)). It can be described as antiferromagnetic (010) layers of magnetic moments lying along the c direction, which are antiferromagnetically coupled along the b direction. For the Ni(2+) ions, the ordered magnetic moment at T = 2.3 K is 2.11(3) micro(B), whereas for Mn(2+) at T = 2.6 K, |m| = 4.64(2) micro(B), consistent with the electronic configurations te (Ni(2+)) and te (Mn(2+)).