Pore‐Structure Control in Metal–Organic Frameworks (MOFs) for Capture of the Greenhouse Gas SF6 with Record Separation

• Published in: Angewandte Chemie International Edition Vol. 61; no. 33; pp. e202207066 - n/a
• Main Authors: Wang, Shao‐Min, Mu, Xuan‐Tong, Liu, Hao‐Ran, Zheng, Su‐Tao, Yang, Qing‐Yuan
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 15.08.2022
• Edition: International ed. in English
• Subjects: Copper; Crystal structure; Electronics industry; Fluorinated Gas; Greenhouse gases; Industrial applications; Metal-organic frameworks; Pore Size Control; Selectivity; Separation; SF6/N2 Separation; Sulfur; Sulfur hexafluoride; SF6/N2 separation; pore size control; MOFs; fluorinated gas

In the electronics industry, the efficient recovery and capture of sulfur hexafluoride (SF6) from SF6/N2 mixtures is of great importance. Herein, three metal–organic frameworks with fine‐tuning pore structures, Cu(peba)2, Ni(pba)2, and Ni(ina)2, were designed for SF6 capture. Among them, Ni(ina)2 ha...