Pd–Ni Bimetallic Nanoparticles Supported on Zro2 as an Efficient Catalyst for Suzuki–Miyaura Reactions
Pd–Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation–reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon–carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the...
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| Published in | Journal of chemical research Vol. 42; no. 8; pp. 419 - 423 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London, England
SAGE Publications
01.08.2018
Sage Publications Ltd |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1747-5198 2047-6507 |
| DOI | 10.3184/174751918X15337409427516 |
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| Abstract | Pd–Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation–reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon–carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the absence of ligand. The excellent catalytic performance of the bimetallic catalyst could be a result of the synergistic effect between the two metal components. The catalyst showed outstanding recyclability during the reaction process; no obvious decrease in catalytic performance was observed after five cycles. |
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| AbstractList | Pd–Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation–reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon–carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the absence of ligand. The excellent catalytic performance of the bimetallic catalyst could be a result of the synergistic effect between the two metal components. The catalyst showed outstanding recyclability during the reaction process; no obvious decrease in catalytic performance was observed after five cycles. |
| Author | Sun, Ying-xin Yao, Xian Zhang, Jia-wei Cai, Chun Zhang, Li-Jie |
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| DOI | 10.3184/174751918X15337409427516 |
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| Keywords | Suzuki–Miyaura coupling alloys bimetallic nanoparticles heterogeneous catalysis nanochemistry |
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| SubjectTerms | Bimetals Carbon Catalysts Catalytic converters Chemical reactions Cross coupling Nanoparticles Palladium Recyclability Shells Substrates Synergistic effect Zirconium dioxide |
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| Title | Pd–Ni Bimetallic Nanoparticles Supported on Zro2 as an Efficient Catalyst for Suzuki–Miyaura Reactions |
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