Mechanistic relationships among PCDDs/Fs, PCNs, PAHs, CIPhs, and CIBzs in municipal waste incineration
An extensive investigation was conducted to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with other organic compounds. PCDD/F, chlorophenols (CIPhs), chlorobenzenes (CIBzs), polyaromatic hydrocarbons (PAHs), and polychlorinated naphthalen...
Saved in:
Published in | Environmental science & technology Vol. 41; no. 13; pp. 4705 - 4710 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
01.07.2007
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | An extensive investigation was conducted to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with other organic compounds. PCDD/F, chlorophenols (CIPhs), chlorobenzenes (CIBzs), polyaromatic hydrocarbons (PAHs), and polychlorinated naphthalenes (PCNs) were analyzed in the boiler exit gases of a field-scale municipal solid waste incinerator under various operating conditions. The TEQ value and the concentration of target compounds changed with incinerator operating conditions. Low mass PAHs and 246-triCIPh increased dramatically during shut downs; the latter was associated with increased 1368- and 1379-TeCDD. A strong correlation was observed between PCNs and PCDFs and adjacent PCNs homologue group were closely related to each other. This suggested that PCN formation is related with chlorination/dechlorination mechanisms similar to PCDFs. PCDDs were related with most of the CIPhs and the high chlorinated benzenes. Most of target compounds except PAHs had a positive correlation (R2 > 0.5) with TEQ and half of them showed a good relationship (R2 > 0.8) with PCDDs/Fs toxic equivalency (TEQ). |
---|---|
AbstractList | An extensive investigation to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with other organic compounds was conducted. PCDD/F, chlorophenols (CIPhs), chlorobenzenes (CIBzs), polyaromatic hydrocarbons (PAHs), and polychlorinated naphthalenes (PCNs) were analyzed in the boiler exit gases of a field-scale municipal solid waste incinerator under various operating conditions. The TEQ value and the concentration of target compounds changed with incinerator operating conditions. A strong correlation was observed between PCNs and PCDFs and adjacent PCNs homologue group were closely related to each other. The results suggested that PCN formation was related with chlorination/dechlorination mechanisms similar to PCDFs. Most of target compounds except PAHs had a positive correlation with TEQ and half of them showed a good relationship with PCDDs/Fs toxic equivalency. An extensive investigation was conducted to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with other organic compounds. PCDD/F, chlorophenols (CIPhs), chlorobenzenes (CIBzs), polyaromatic hydrocarbons (PAHs), and polychlorinated naphthalenes (PCNs) were analyzed in the boiler exit gases of a field-scale municipal solid waste incinerator under various operating conditions. The TEQ value and the concentration of target compounds changed with incinerator operating conditions. Low mass PAHs and 246-triCIPh increased dramatically during shut downs; the latter was associated with increased 1368- and 1379-TeCDD. A strong correlation was observed between PCNs and PCDFs and adjacent PCNs homologue group were closely related to each other. This suggested that PCN formation is related with chlorination/dechlorination mechanisms similar to PCDFs. PCDDs were related with most of the CIPhs and the high chlorinated benzenes. Most of target compounds except PAHs had a positive correlation (R2 > 0.5) with TEQ and half of them showed a good relationship (R2 > 0.8) with PCDDs/Fs toxic equivalency (TEQ). |
Author | OH, Jeong-Eun GULLETT, Brian RYAN, Shawn TOUATI, Abderrahmane |
Author_xml | – sequence: 1 givenname: Jeong-Eun surname: OH fullname: OH, Jeong-Eun organization: Department of Environmental Engineering, Pusan National University, Pusan, Korea, Republic of – sequence: 2 givenname: Brian surname: GULLETT fullname: GULLETT, Brian organization: Office of Research and Development, National Risk Management Research Laboratory, U.S. Environmental Protection Agency (E305-01), Research Triangle Park, North Carolina, 27711, United States – sequence: 3 givenname: Shawn surname: RYAN fullname: RYAN, Shawn organization: Office of Research and Development, National Risk Management Research Laboratory, U.S. Environmental Protection Agency (E305-01), Research Triangle Park, North Carolina, 27711, United States – sequence: 4 givenname: Abderrahmane surname: TOUATI fullname: TOUATI, Abderrahmane organization: ARCADIS G & M, P.O. Box 13109, Research Triangle Park, North Carolina 27709, United States |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18903105$$DView record in Pascal Francis https://www.ncbi.nlm.nih.gov/pubmed/17695917$$D View this record in MEDLINE/PubMed |
BookMark | eNpFkMtOwzAURC1URB-w4AdQNrAi1I84iZclpbRSgS5AYhfd2g41SpwQJ0Lw9RgoYjMzGh2NdO8YDWxtNUKnBF8RTMlUOxxTkZD4AI0IpzjkKScDNMKYsFCw-HmIxs69Yowpw-kRGpIkFlyQZISKOy13YI3rjAxaXUJnaut2pnEBVLV9CTbZfO6mC3fp0_23zpZes9Vm5w2s8vH60wXGBlVvjTQNlME7uE77Shqr25_FY3RYQOn0yd4n6Glx85gtw_XD7SqbrcOGJrgLJdc84hiiVNGCiyRSNNJECJGIbSql5IXgoBSmIGTEfa10QUQEW6YYyC1mE3Txu9u09VuvXZdXxkldlmB13bucRCmJeZx68GwP9ttKq7xpTQXtR_73GQ-c7wFwEsqiBX-O--dSgRnBnH0B4JZyEg |
CODEN | ESTHAG |
ContentType | Journal Article |
Copyright | 2007 INIST-CNRS |
Copyright_xml | – notice: 2007 INIST-CNRS |
DBID | IQODW CGR CUY CVF ECM EIF NPM 7ST C1K SOI |
DOI | 10.1021/es0629716 |
DatabaseName | Pascal-Francis Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed Environment Abstracts Environmental Sciences and Pollution Management Environment Abstracts |
DatabaseTitle | MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) Environment Abstracts Environmental Sciences and Pollution Management |
DatabaseTitleList | Environment Abstracts MEDLINE |
Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: EIF name: MEDLINE url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/medline/basic-search sourceTypes: Index Database |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Applied Sciences Engineering Environmental Sciences |
EISSN | 1520-5851 |
EndPage | 4710 |
ExternalDocumentID | 17695917 18903105 |
Genre | Journal Article |
GroupedDBID | --- -DZ -~X ..I .DC .HR .K2 08R 186 1WB 3R3 4.4 42X 4R4 53G 55A 5GY 5VS 63O 6TJ 7~N 85S 8WZ A6W AABXI AAYOK ABFRP ABHMW ABMVS ABOGM ABPPZ ABPTK ABQRX ABTAH ABUCX ACGFS ACGOD ACIWK ACJ ACKIV ACPRK ACS ADHLV ADMHC AEESW AENEX AETEA AFDAS AFEFF AFRAH AGHSJ AGXLV AHGAQ ALMA_UNASSIGNED_HOLDINGS ANTXH AQSVZ BAANH BKOMP CS3 EBS ED~ EJD F5P GGK GNL IH9 IHE IQODW JG~ LG6 MS~ MVM MW2 NHB OHT PQQKQ RNS ROL RXW TAE TN5 TWZ U5U UBC UBX UBY UHB UI2 UKR UPT UQL VF5 VG9 VJK VOH VQA W1F WH7 XFK XSW XZL YV5 YZZ ZCA ZCG ZY4 ~A~ AAHBH ABJNI ADUKH CGR CUPRZ CUY CVF ECM EIF NPM 7ST C1K SOI |
ID | FETCH-LOGICAL-p270t-c5e5450a48d2f5974d24e199979b8ccc5f95add02a9c45997def194ab3d3acb03 |
ISSN | 0013-936X |
IngestDate | Fri Aug 16 01:21:46 EDT 2024 Sat Sep 28 08:39:18 EDT 2024 Sun Oct 22 16:06:42 EDT 2023 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 13 |
Keywords | Cluster analysis Dioxin derivatives Hydrocarbon Toxicity Urban waste Pollutant formation Polycyclic aromatic compound Operating conditions Incineration plant Correlation analysis Chlorine Organic compounds Solid waste Toxic equivalency factor Reaction mechanism Phenols Aromatic compound Principal component analysis |
Language | English |
License | CC BY 4.0 |
LinkModel | OpenURL |
MergedId | FETCHMERGED-LOGICAL-p270t-c5e5450a48d2f5974d24e199979b8ccc5f95add02a9c45997def194ab3d3acb03 |
Notes | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
PMID | 17695917 |
PQID | 14816568 |
PQPubID | 23462 |
PageCount | 6 |
ParticipantIDs | proquest_miscellaneous_14816568 pubmed_primary_17695917 pascalfrancis_primary_18903105 |
PublicationCentury | 2000 |
PublicationDate | 2007-07-01 |
PublicationDateYYYYMMDD | 2007-07-01 |
PublicationDate_xml | – month: 07 year: 2007 text: 2007-07-01 day: 01 |
PublicationDecade | 2000 |
PublicationPlace | Washington, DC |
PublicationPlace_xml | – name: Washington, DC – name: United States |
PublicationTitle | Environmental science & technology |
PublicationTitleAlternate | Environ Sci Technol |
PublicationYear | 2007 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
SSID | ssj0002308 |
Score | 2.25004 |
Snippet | An extensive investigation was conducted to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with... An extensive investigation to understand polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation mechanisms and their relationship with other organic... |
SourceID | proquest pubmed pascalfrancis |
SourceType | Aggregation Database Index Database |
StartPage | 4705 |
SubjectTerms | Applied sciences Atmospheric pollution Chlorobenzenes - chemistry Combustion and energy production Exact sciences and technology Incineration Pollution Pollution sources. Measurement results Polycyclic Compounds - chemistry Refuse Disposal Urban and domestic wastes Wastes |
Title | Mechanistic relationships among PCDDs/Fs, PCNs, PAHs, CIPhs, and CIBzs in municipal waste incineration |
URI | https://www.ncbi.nlm.nih.gov/pubmed/17695917 https://search.proquest.com/docview/14816568 |
Volume | 41 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnZ3Pb9MwFMctGBc4IBiMlcHwgRsNyw-7sY8la-jQ2k3QSr1Fju2oPdBWSyq0_fU8Oz-rgfhxSVtLiaK8T5_tl_e-D6H3QUYFyzR1Br4MHKKkcpgyPTQyHSpGfJ3aCu_JdDCeky8LumijSra6pEg_yrtf1pX8j1VhDOxqqmT_wbLNRWEAvoN94QgWhuNf2XiiTd2ulVpus9qWq23-YWh7CF1H5-dgpzgu1fijafk5HJe6AhfXy7zO3owuPt3Z1NiJKRdZbU0cXQABxoGY-sDWgHUYv62Qq-sqpbYgFfei9VfLMpEG7skZ7RocP1vp76JErIPp19sqKrsUP9o84Y0RJbeuLFX6Bnzkd1GlBNRBi7BJcG0csRc4PLBNDBtHTLwucEHHrZLQpZ0puv55z_3DgsWAkLsD30hjtXNc_V5_epXE88vLZDZazB6iR37IqckDHUbfmukb9mSsbnth7rCWo_K9s-bCJoNW5PAnysruJ7_fnthlyuwZelrtL_CwhOU5eqDXh-hJR3XyEB3tmQ5X3j1_gbIOT3iPJ2x5wpanszjvY8MSHIGkPrYc9TFQhC1FeLXGDUXYUoS7FL1E83g0i8ZO1YfD2fqhWziSalhnu4Iw5WdmA6p8oo18RchTJqWkGacwTbq-4JJQGFY68zgRaaACIVM3OEIH681aHyOsUukzN3VVFhBYyGvOvDClmriMC9iLyB463XuwybbUXEk8xo2ILe2hd_WTTsARmrdbANtml8MelhklKdZDr0oDtOeGA065F77-47kn6HFL6xt0UNzs9FtYdBbpqYXkJ78hgug |
link.rule.ids | 315,786,790,27955,27956 |
linkProvider | American Chemical Society |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Mechanistic+Relationships+Among+PCDDs%2FFs%2C+PCNs%2C+PAHs%2C+CIPhs%2C+and+CIBzs+in+Municipal+Waste+Incineration&rft.jtitle=Environmental+science+%26+technology&rft.au=Oh%2C+Jeong-Eun&rft.au=Gullett%2C+Brian&rft.au=Ryan%2C+Shawn&rft.au=Touati%2C+Abderrahmane&rft.date=2007-07-01&rft.issn=0013-936X&rft.volume=41&rft.issue=13&rft.spage=4705&rft.epage=4705&rft_id=info:doi/10.1021%2Fes0629716&rft.externalDBID=NO_FULL_TEXT |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-936X&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-936X&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-936X&client=summon |