A Planar‐Structured Dinuclear Cobalt(II) Complex with Indirect Synergy for Photocatalytic CO2‐to‐CO Conversion

• Published in: Angewandte Chemie International Edition Vol. 63; no. 45; pp. e202411639 - n/a
• Main Authors: Gong, Yun‐Nan, Zhao, Si‐Qi, Wang, Hong‐Juan, Ge, Zhao‐Ming, Liao, Chen, Tao, Ke‐Ying, Zhong, Di‐Chang, Sakai, Ken, Lu, Tong‐Bu
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 04.11.2024
• Edition: International ed. in English
• Subjects: Carbon dioxide; Carbon monoxide; Catalysis; Catalytic activity; Catalytic converters; Chemical reduction; CO2 reduction; Cobalt; Cobalt compounds; Coordination compounds; dinuclear metal complex; dinuclear metal synergistic catalysis (DMSC); Efficiency; Electron transfer; Mass transfer; Metal complexes; Microenvironments; molecular photocatalysis; Photocatalysis; Photochemicals; planar structure; Planar structures

Dinuclear metal synergistic catalysis (DMSC) has been proved an effective approach to enhance catalytic efficiency in photocatalytic CO2 reduction reaction, while it remains challenge to design dinuclear metal complexes that can show DMSC effect. The main reason is that the influence of the microenv...