Microenvironment Engineering for the Electrocatalytic CO2 Reduction Reaction

Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent r...

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Published inAngewandte Chemie International Edition Vol. 61; no. 39; pp. e202207252 - n/a
Main Authors Lv, Jing‐Jing, Yin, Ruonan, Zhou, Limin, Li, Jun, Kikas, Reddu, Xu, Ting, Wang, Zheng‐Jun, Jin, Huile, Wang, Xin, Wang, Shun
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 26.09.2022
EditionInternational ed. in English
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Abstract Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. We categorize the microenvironment based on the components relevant to electrocatalytic active sites, i.e., the catalyst surface, substrate, co‐reactants, electrolyte, membrane, and reactor. Supported by most of the reported articles, the relevant factors affecting the catalytic performance of eCO2RR are then discussed in detail, and existing challenges and potential solutions are mentioned. Perspectives for the future research on eCO2RR, including the integration of different microenvironment factors, the extension to industrial application by coupling with carbon capture and conversion, and separation of products, are also discussed. This Review summarizes the impact of the microenvironment, including the catalyst surface, substrate, co‐reactants, electrolyte, membrane, and reactor, on the electrocatalytic CO2 reduction reaction (CO2RR). Different microenvironmental factors are discussed in the context of industrial applications, including coupling of CO2RR to carbon capture and conversion.
AbstractList Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. We categorize the microenvironment based on the components relevant to electrocatalytic active sites, i.e., the catalyst surface, substrate, co‐reactants, electrolyte, membrane, and reactor. Supported by most of the reported articles, the relevant factors affecting the catalytic performance of eCO2RR are then discussed in detail, and existing challenges and potential solutions are mentioned. Perspectives for the future research on eCO2RR, including the integration of different microenvironment factors, the extension to industrial application by coupling with carbon capture and conversion, and separation of products, are also discussed.
Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. We categorize the microenvironment based on the components relevant to electrocatalytic active sites, i.e., the catalyst surface, substrate, co‐reactants, electrolyte, membrane, and reactor. Supported by most of the reported articles, the relevant factors affecting the catalytic performance of eCO2RR are then discussed in detail, and existing challenges and potential solutions are mentioned. Perspectives for the future research on eCO2RR, including the integration of different microenvironment factors, the extension to industrial application by coupling with carbon capture and conversion, and separation of products, are also discussed. This Review summarizes the impact of the microenvironment, including the catalyst surface, substrate, co‐reactants, electrolyte, membrane, and reactor, on the electrocatalytic CO2 reduction reaction (CO2RR). Different microenvironmental factors are discussed in the context of industrial applications, including coupling of CO2RR to carbon capture and conversion.
Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2 RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. We categorize the microenvironment based on the components relevant to electrocatalytic active sites, i.e., the catalyst surface, substrate, co-reactants, electrolyte, membrane, and reactor. Supported by most of the reported articles, the relevant factors affecting the catalytic performance of eCO2 RR are then discussed in detail, and existing challenges and potential solutions are mentioned. Perspectives for the future research on eCO2 RR, including the integration of different microenvironment factors, the extension to industrial application by coupling with carbon capture and conversion, and separation of products, are also discussed.Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2 RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. We categorize the microenvironment based on the components relevant to electrocatalytic active sites, i.e., the catalyst surface, substrate, co-reactants, electrolyte, membrane, and reactor. Supported by most of the reported articles, the relevant factors affecting the catalytic performance of eCO2 RR are then discussed in detail, and existing challenges and potential solutions are mentioned. Perspectives for the future research on eCO2 RR, including the integration of different microenvironment factors, the extension to industrial application by coupling with carbon capture and conversion, and separation of products, are also discussed.
Author Li, Jun
Wang, Shun
Wang, Xin
Yin, Ruonan
Jin, Huile
Zhou, Limin
Wang, Zheng‐Jun
Lv, Jing‐Jing
Kikas, Reddu
Xu, Ting
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Snippet Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2RR), as previously reviewed elsewhere, we herein extend...
Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2 RR), as previously reviewed elsewhere, we herein extend...
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wiley
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StartPage e202207252
SubjectTerms Carbon dioxide
Carbon sequestration
Catalysts
Chemical reduction
Electrochemical CO2 Reduction Reaction
Industrial applications
Microenvironment Engineering
Microenvironments
Product Selectivity
Substrates
Title Microenvironment Engineering for the Electrocatalytic CO2 Reduction Reaction
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.202207252
https://www.proquest.com/docview/2715421045
https://www.proquest.com/docview/2688569869
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