Hydrogen‐Bonded Organic Framework Ultrathin Nanosheets for Efficient Visible‐Light Photocatalytic CO2 Reduction

• Published in: Angewandte Chemie International Edition Vol. 61; no. 43; pp. e202211482 - n/a
• Main Authors: Yu, Baoqiu, Meng, Ting, Ding, Xu, Liu, Xiaolin, Wang, Hailong, Chen, Baotong, Zheng, Tianyu, Li, Wen, Zeng, Qingdao, Jiang, Jianzhuang
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 24.10.2022
• Edition: International ed. in English
• Subjects: Carbon dioxide; Carbon Dioxide Reduction; Graphene; Guanine; Hydrogen-Bonded Organic Frameworks; Immobilization; Nanosheets; Nickel; Post-Modification; Pyridines; Pyrolytic graphite; Reduction; Selectivity; Sonication; Supramolecular frameworks; Visible Light Photocatalysis
• ISSN: 1433-7851; 1521-3773; 1521-3773
• DOI: 10.1002/anie.202211482

Post‐modification of robust guanine‐quadruplex‐linked 2,2′‐pyridine‐containing HOF‐25 with Ni(ClO4)2 ⋅ 6 H2O followed by exfoliation using sonication method affords hydrogen‐bonded organic framework (HOF) nanosheets (NSs) of HOF‐25‐Ni in the yield of 56 %. TEM and AFM technologies disclose the ultra...