Redox‐Active Crystalline Coordination Catalyst for Hybrid Electrocatalytic Methanol Oxidation and CO2 Reduction

• Published in: Angewandte Chemie International Edition Vol. 61; no. 34; pp. e202207282 - n/a
• Main Authors: Sun, Sheng‐Nan, Dong, Long‐Zhang, Li, Jia‐Ru, Shi, Jing‐Wen, Liu, Jiang, Wang, Yi‐Rong, Huang, Qing, Lan, Ya‐Qian
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 22.08.2022
• Edition: International ed. in English
• Subjects: Anodizing; Bifunctional Crystalline Catalysts; Carbon dioxide; Catalysts; Clusters; Coordination; Crystalline Coordination Compounds; Electric fields; Electrowinning; Energy conversion; Energy conversion efficiency; Hybrid CO2 Electroreduction; Irradiation; Light irradiation; Methanol; Methanol Oxidation; Oxidation; Radiation

Hybrid CO2 electroreduction (HCER) is recognized as an important strategy to improve the total value of redox products and energy conversion efficiency. In this work, a coordination catalyst model system (Ni8‐TET with active oxidation sites, Ni‐TPP with active reduction sites and PCN‐601 with redox‐...