Isomeric Cu(I) Azolate Frameworks Showing Contrasting Electrocatalytic CO2 Reduction Selectivities and Stabilities

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 21; no. 4; pp. e2408510 - n/a
• Main Authors: Zheng, Kai, Hu, Ding‐Yi, Wang, Chao, Liang, Zi‐Jun, Zhang, Xue‐Wen, Xiao, Xian‐Xian, Wu, Jun‐Xi, Zhuo, Lin‐Ling, Lin, Duo‐Yu, Zhou, Dong‐Dong, Zhang, Jie‐Peng
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.01.2025
• Subjects: Carbon dioxide; carbon dioxide reduction; Chemical composition; Chemical reduction; Coordination; coordination mode; Electrocatalysts; ethylene; metal azolate frameworks; Selectivity; supramolecular isomer

Metal‒organic frameworks have attracted wide interest in the electrocatalytic CO2 reduction reaction (eCO2RR), but their differences of performances originated from chemical composition and stabilities are rarely concerned. Here, isomeric Cu(I) triazolate frameworks (MAF‐2Fa and MAF‐2Fb) with simila...