Kinetic acidity of aliphatic hydrocarbons. Hydrogen isotope exchange with cesium cyclohexylamide in cyclohexylamine
Kinetic acidities are reported for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, nortricyclene, and adamantane by tritiodeprotonation or deuteriodeprotonation in cyclohexylamine catalyzed by cesium cyclohexylamide.
Saved in:
| Published in | Journal of the American Chemical Society Vol. 127; no. 25; pp. 9290 - 9297 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington, DC
American Chemical Society
29.06.2005
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Kinetic acidities are reported for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, nortricyclene, and adamantane by tritiodeprotonation or deuteriodeprotonation in cyclohexylamine catalyzed by cesium cyclohexylamide. |
|---|---|
| AbstractList | Kinetic acidities are reported for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, nortricyclene, and adamantane by tritiodeprotonation or deuteriodeprotonation in cyclohexylamine catalyzed by cesium cyclohexylamide. |
| Author | DART, Edward C STREITWIESER, Andrew TAYLOR, David R KEEVIL, Thomas A |
| Author_xml | – sequence: 1 givenname: Andrew surname: STREITWIESER fullname: STREITWIESER, Andrew organization: Department of Chemistry, University of California, Berkeley, California 94720-1460, United States – sequence: 2 givenname: Thomas A surname: KEEVIL fullname: KEEVIL, Thomas A organization: Department of Chemistry, University of California, Berkeley, California 94720-1460, United States – sequence: 3 givenname: David R surname: TAYLOR fullname: TAYLOR, David R organization: Department of Chemistry, University of California, Berkeley, California 94720-1460, United States – sequence: 4 givenname: Edward C surname: DART fullname: DART, Edward C organization: Department of Chemistry, University of California, Berkeley, California 94720-1460, United States |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16909081$$DView record in Pascal Francis https://www.ncbi.nlm.nih.gov/pubmed/15969612$$D View this record in MEDLINE/PubMed |
| BookMark | eNpV0L1OwzAUBWALFdEfGHgB5AW2gO3Ejj2iCiiiEgvMlWPfNC6JHeJUNG9PK4oQ09U5-nSGO0UjHzwgdEnJLSWM3m004TQV4uMETShnJOGUiRGaEEJYkkuRjtE0xs0-ZkzSMzSmXAklKJug-OI89M5gbZx1_YBDiXXt2kofymqwXTC6K4KPt3hxSGvw2MXQhxYw7Eyl_Rrwl-srbCC6bYPNYOpQwW6odeMsYOf_Vx7O0Wmp6wgXxztD748Pb_NFsnx9ep7fL5OWpapPOJiUEm0zwVWZlrk0uaGilJILwzUVpFBcC8lyWxipWEaAMmsApLWW5BmkM3Tzs9t24XMLsV81Lhqoa-0hbONK5EqQVPA9vDrCbdGAXbWda3Q3rH7ftAfXR6Cj0XXZaW9c_HNCEUUkTb8Bd5d6XA |
| CODEN | JACSAT |
| ContentType | Journal Article |
| Copyright | 2005 INIST-CNRS |
| Copyright_xml | – notice: 2005 INIST-CNRS |
| DBID | IQODW CGR CUY CVF ECM EIF NPM 7X8 |
| DOI | 10.1021/ja051366k |
| DatabaseName | Pascal-Francis Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed MEDLINE - Academic |
| DatabaseTitle | MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) MEDLINE - Academic |
| DatabaseTitleList | MEDLINE MEDLINE - Academic |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: EIF name: MEDLINE url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/medline/basic-search sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5126 |
| EndPage | 9297 |
| ExternalDocumentID | 15969612 16909081 |
| Genre | Research Support, U.S. Gov't, Non-P.H.S Journal Article |
| GroupedDBID | --- -DZ -ET -~X .DC .GJ .HR .K2 186 1WB 3EH 3O- 4.4 41~ 53G 55A 5GY 5RE 5VS 6TJ 7~N 85S AABXI AAUPJ AAYJJ AAYOK ABDEX ABFRP ABHMW ABMVS ABPPZ ABPTK ABQRX ABTAH ABUCX ABWLT ACBEA ACBNA ACGFO ACGFS ACJ ACKIV ACNCT ACS ADHLV AEESW AENEX AETEA AFDAS AFEFF AFFDN AFFNX AGHSJ AGJRR AGXLV AHGAQ AI. AIDAL ALMA_UNASSIGNED_HOLDINGS ANTXH AQSVZ BAANH BKOMP CS3 D0S DU5 EBS ED~ EJD F5P GGK GNL IH2 IH9 IHE IQODW JG~ LG6 MVM NHB OHT P-O P2P RNS ROL RXW TAE TAF TN5 UBC UBX UHB UI2 UKR UPT UQL VF5 VG9 VH1 VQA W1F WH7 X7L XFK XOL XSW YQT YXA YXE YYP YZZ ZCA ZCG ZE2 ZGI ZHY ZY4 ~02 AAHBH ABJNI CGR CUPRZ CUY CVF ECM EIF NPM 7X8 |
| ID | FETCH-LOGICAL-p239t-5ec310ad4659f3f78c7c16f8856c5a160b95a6827dbc89240e12dcee8ddd074e3 |
| ISSN | 0002-7863 |
| IngestDate | Fri Oct 25 10:18:05 EDT 2024 Sat Sep 28 07:43:23 EDT 2024 Sun Oct 29 17:07:18 EDT 2023 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 25 |
| Keywords | Alkali metal Compounds Catalytic reaction Base catalysis Isotope exchange Thermal reaction Experimental study Organic solvent Alkane Kinetic parameter Rate constant Catalyst activity Mass spectrometry Liquid scintillation Deprotonation |
| Language | English |
| License | CC BY 4.0 |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-p239t-5ec310ad4659f3f78c7c16f8856c5a160b95a6827dbc89240e12dcee8ddd074e3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PMID | 15969612 |
| PQID | 67960365 |
| PQPubID | 23479 |
| PageCount | 8 |
| ParticipantIDs | proquest_miscellaneous_67960365 pubmed_primary_15969612 pascalfrancis_primary_16909081 |
| PublicationCentury | 2000 |
| PublicationDate | 2005-06-29 |
| PublicationDateYYYYMMDD | 2005-06-29 |
| PublicationDate_xml | – month: 06 year: 2005 text: 2005-06-29 day: 29 |
| PublicationDecade | 2000 |
| PublicationPlace | Washington, DC |
| PublicationPlace_xml | – name: Washington, DC – name: United States |
| PublicationTitle | Journal of the American Chemical Society |
| PublicationTitleAlternate | J Am Chem Soc |
| PublicationYear | 2005 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| SSID | ssj0004281 |
| Score | 1.8681872 |
| Snippet | Kinetic acidities are reported for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, nortricyclene, and adamantane... |
| SourceID | proquest pubmed pascalfrancis |
| SourceType | Aggregation Database Index Database |
| StartPage | 9290 |
| SubjectTerms | Amides - chemistry Cesium - chemistry Chemistry Cyclohexylamines - chemistry Deuterium - chemistry Deuterium Exchange Measurement - methods Exact sciences and technology Hydrocarbons - chemistry Kinetics Kinetics and mechanisms Organic chemistry Organometallic Compounds - chemistry Reactivity and mechanisms Time Factors |
| Title | Kinetic acidity of aliphatic hydrocarbons. Hydrogen isotope exchange with cesium cyclohexylamide in cyclohexylamine |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/15969612 https://search.proquest.com/docview/67960365 |
| Volume | 127 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9NAEF6FcoAL4k1KKXvgZhnFdna9PlahKALBhVbqLVrvQ7FobSt21KY_or-Z2YfjOGol4GIl63gd7Xwafzv-ZgahT0JEKSVpFuZRQmGDkrOQySQNpxLoulaRYraW3o-fdH4-_XZBLkajux3V0rrNP4vbe_NK_seqMAZ2NVmy_2DZ7aQwAJ_BvnAEC8Pxr2z8HSiiLbgqCumlFUCr66WtwrrcSHg48VVu7h7MzTeYKCiaqq1qFagbl_PrxeeqKdZXgdiIy2qpbjaAk0LaeiKDoXIoHOrJ7E6CShlsixB4Seg2itOuVNFem7oUqz0xpXX58Iy-7EVLfZS1jypYBX6vcfzCXcKR6zztA75dCIMYqZWPc_RuOWXe03Vu2dUM8PiLyY6XBUo3udf9A2GxbQfA0ySU_t79DViuvrI4AAJHM-rF28Na292pR-hxDI7LeMyT2a8-zzZmUbedMn-3q1QVmypW_p62z5ObxehseQPLrV2PlIc3MZbMnD1Hz7zh8ImD1As0UuVL9GTWNf97hRoPLeyhhSuNt9DCA2jhDlrYQwt30MIGWthBC-9BCxcl3oPWa3T-9fRsNg99f46wjpOsDYkSsDngckpJphOdMpGKiGrGCBWER3SSZ4RTFqcyFwz2-RMVxRJIGZNSAnNVyRt0UFaleocwkNQ003nEtc6nWargokhIyYUpkJfpyRgdD5ZyUbtaLAvzljcDWjtGH7u1XcBSmbdevFTVulmYQCnQNDJGb92S99d6Ox0-eOY9etrj9QgdtKu1-gAktM2PLTL-AHN5jb4 |
| link.rule.ids | 315,783,787,27936,27937 |
| linkProvider | American Chemical Society |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Kinetic+acidity+of+aliphatic+hydrocarbons.+Hydrogen+isotope+exchange+with+cesium+cyclohexylamide+in+cyclohexylamine&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=Streitwieser%2C+Andrew&rft.au=Keevil%2C+Thomas+A&rft.au=Taylor%2C+David+R&rft.au=Dart%2C+Edward+C&rft.date=2005-06-29&rft.issn=0002-7863&rft.volume=127&rft.issue=25&rft.spage=9290&rft_id=info:doi/10.1021%2Fja051366k&rft_id=info%3Apmid%2F15969612&rft.externalDocID=15969612 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7863&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7863&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7863&client=summon |