Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries

• Published in: Angewandte Chemie International Edition Vol. 63; no. 5
• Main Authors: Guan, De‐Hui, Wang, Xiao‐Xue, Song, Li‐Na, Miao, Cheng‐Lin, Li, Jian‐You, Yuan, Xin‐Yuan, Ma, Xin‐Yue, Xu, Ji‐Jing
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 25.01.2024
• Edition: International ed. in English
• Subjects: Air batteries; Cathodes; Electrochemical Stability; Electrochemistry; Electrolytes; Interface stability; Ion currents; Li-Air Battery; Lithium; Lithium batteries; Li–Metal Battery; Molten salt electrolytes; Polyoxometallates; Solid Electrolyte; Solid electrolytes; Strategy; Voltage

Solid‐state lithium (Li) batteries promise both high energy density and safety while existing solid‐state electrolytes (SSEs) fail to satisfy the rigorous requirements of battery operations. Herein, novel polyoxometalate SSEs, Li3PW12O40 and Li3PMo12O40, are synthesized, which exhibit excellent inte...