Flexible Cuprous Triazolate Frameworks as Highly Stable and Efficient Electrocatalysts for CO2 Reduction with Tunable C2H4/CH4 Selectivity

• Published in: Angewandte Chemie International Edition Vol. 61; no. 28
• Main Authors: Zhuo, Lin‐Ling, Chen, Pin, Zheng, Kai, Zhang, Xue‐Wen, Wu, Jun‐Xi, Lin, Duo‐Yu, Liu, Si‐Yang, Wang, Zhi‐Shuo, Liu, Jin‐Yu, Zhou, Dong‐Dong, Zhang, Jie‐Peng
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 11.07.2022
• Edition: International ed. in English
• Subjects: Carbon dioxide; Catalysts; CO2 reduction; Computer applications; Copper; dinuclear copper sites; electrocatalysis; Electrocatalysts; flexibility; Intermediates; Ligands; Metal-organic frameworks; Methane; Reaction intermediates; Selectivity; Steric hindrance

Cu‐based metal–organic frameworks have attracted much attention for electrocatalytic CO2 reduction, but they are generally instable and difficult to control the product selectivity. We report flexible Cu(I) triazolate frameworks as efficient, stable, and tunable electrocatalysts for CO2 reduction to...