A Ni(salen)‐Based Metal–Organic Framework: Synthesis, Structure, and Catalytic Performance for CO2 Cycloaddition with Epoxides

• Published in: European journal of inorganic chemistry Vol. 2017; no. 43; pp. 4982 - 4989
• Main Authors: Fan, Yamei, Li, Jiawei, Ren, Yanwei, Jiang, Huanfeng
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 24.11.2017; Wiley Subscription Services, Inc
• Subjects: Carbon dioxide; Carbon dioxide fixation; Catalysis; Chemical synthesis; Chemistry; Chemistry, Inorganic & Nuclear; Crosslinking; Cyclic carbonates; Cycloaddition; Heterogeneous catalysis; Infrared analysis; Inorganic chemistry; Lamellar structure; Lewis acid; Metallosalen ligands; Metal–organic frameworks; Nickel; Nitrogen; Physical Sciences; Porosity; Science & Technology; Selectivity; Single crystals; Thermogravimetric analysis; MOF; CONVERSION; DIOXIDE; Cyclic carbonates; Heterogeneous catalysis; Carbon dioxide fixation; Metallosalen ligands; ASYMMETRIC CYANOSILYLATION; SALEN; Metal-organic frameworks; HETEROGENEOUS CATALYST; EFFICIENT; CAPTURE; FIXATION

A three‐dimensional (3D) chiral metal–organic framework [Cd2{Ni(salen)}(DMF)3]·4DMF·7H2O (1) based on a new enantiopure tetracarboxyl‐functionalized metallosalen Ni(H4salen) {where H6salen is (R,R)‐N,N′‐bis[3‐tert‐butyl‐5‐(3,5‐dicarboxybenzyl)salicylidene]‐1,2‐diphenylethylenediame} was synthesized...