A comparative on the thermal decomposition and fire‐extinguishing performance of C5F8 and C5F7Cl

• Published in: International journal of quantum chemistry Vol. 123; no. 20
• Main Authors: Chang, Zhenxiang, Yu, Rourou, Li, Shukai, Guo, Yueying, Tan, Zhaoyang, Zhang, Xiao, Liu, Jiexiang
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 15.10.2023; Wiley Subscription Services, Inc
• Subjects: Alkenes; Chemistry; Chlorine; Cycloalkanes; density functional theory; Extinguishing; fire suppression; Fluorination; Halon substitute; Physical chemistry; Pyrolysis; pyrolysis mechanism; Quantum physics; theoretical and experimental insights; Thermal decomposition

Compared with fluorinated cycloalkanes and liner olefins, the degradation of chlorofluorocycloolefins is much easier with good environmental friendliness. However, the fire‐extinguishing performance of chlorofluorocycloolefins has been rarely explored. In this study, the fire‐extinguishing performan...