Dicationic ionic liquid‐grafted UiO‐66 as efficient catalyst for CO2 conversion into cyclocarbonate under cocatalyst‐free and solventless conditions

• Published in: Applied organometallic chemistry Vol. 38; no. 11
• Main Authors: Li, Fangfang, Hou, Xiaofang, Zhou, Ying‐Hua
• Format: Journal Article
• Language: English
• Published: Chichester Wiley Subscription Services, Inc 01.11.2024
• Subjects: Carbon dioxide; Catalysts; Cycloaddition; Dicarboxylic acids; epoxide cycloaddition; heterogeneous catalysis; ionic liquid; Ionic liquids; Metal-organic frameworks; Performance evaluation; Recyclability; Self-assembly; Substrates; Terephthalic acid; UiO‐66

CO2 chemical fixation offers a feasible approach for carbon mitigation and high‐value utilization, but it is still challenging to develop an efficient catalyst for CO2 conversion into cyclic carbonate. Herein, the triethylenediamine‐derived dicationic ionic liquids (DIL‐X, X = Cl, Br, and I) were gr...