Ligand-dependent structural diversity and optimizable CO2 chemical fixation activities of Cu-doped polyoxo-titanium clusters

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 33; pp. 11451 - 11457
• Main Authors: Lin, Xin, Ying-Hua, Yu, Guang-Hui Chen, Qiao-Hong, Li, Zhang, Lei, Zhang, Jian
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 22.08.2023
• Subjects: Acetic acid; Carbon dioxide; Catalytic activity; Clusters; Copper; Cycloaddition; Ethanol; Lewis acid; Ligands; Steric hindrance; Titanium; Titanium oxides

Heterometallic oxo clusters have been attracting intensive interest due to their unique properties originating from the synergistic interactions between different components. Herein, we report the construction and catalytic applications of a family of copper-doped polyoxo-titanium clusters (Cu-PTCs)...