Fluxional Bonds in Planar B19−, Tubular Ta@B20−, and Cage‐Like B39
Based on detailed bonding analyses on the fluxional behaviors of planar B19−, tubular Ta@B20−, and cage‐like B39−, we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc. Detai...
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| Published in | Journal of computational chemistry Vol. 40; no. 9; pp. 966 - 970 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Hoboken, USA
John Wiley & Sons, Inc
05.04.2019
Wiley Subscription Services, Inc |
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| Abstract | Based on detailed bonding analyses on the fluxional behaviors of planar B19−, tubular Ta@B20−, and cage‐like B39−, we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc.
Detailed bonding analyses on fluxional boron nanoclusters suggest the existence of fluxional bonds in electron‐deficient systems with low energy barriers as an extension of the classical localized bonds and delocalized bonds in chemistry. |
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| AbstractList | Based on detailed bonding analyses on the fluxional behaviors of planar B19−, tubular Ta@B20−, and cage‐like B39−, we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc.
Detailed bonding analyses on fluxional boron nanoclusters suggest the existence of fluxional bonds in electron‐deficient systems with low energy barriers as an extension of the classical localized bonds and delocalized bonds in chemistry. Based on detailed bonding analyses on the fluxional behaviors of planar B19−, tubular Ta@B20−, and cage‐like B39−, we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc. Based on detailed bonding analyses on the fluxional behaviors of planar B19 - , tubular Ta@B20 - , and cage-like B39 - , we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc.Based on detailed bonding analyses on the fluxional behaviors of planar B19 - , tubular Ta@B20 - , and cage-like B39 - , we propose the concept of fluxional bonds in boron nanoclusters as an extension of the classical localized bonds and delocalized bonds in chemistry. © 2018 Wiley Periodicals, Inc. |
| Author | Lu, Hai‐Gang Yan, Miao Li, Hai‐Ru Mu, Yue‐Wen Zhao, Xiao‐Yun Li, Si‐Dian Lu, Xiao‐Qin |
| Author_xml | – sequence: 1 givenname: Miao surname: Yan fullname: Yan, Miao organization: Shanxi University – sequence: 2 givenname: Hai‐Ru surname: Li fullname: Li, Hai‐Ru organization: Shanxi University – sequence: 3 givenname: Xiao‐Yun surname: Zhao fullname: Zhao, Xiao‐Yun organization: Shanxi University – sequence: 4 givenname: Xiao‐Qin surname: Lu fullname: Lu, Xiao‐Qin organization: Shanxi University – sequence: 5 givenname: Yue‐Wen surname: Mu fullname: Mu, Yue‐Wen organization: Shanxi University – sequence: 6 givenname: Hai‐Gang surname: Lu fullname: Lu, Hai‐Gang organization: Shanxi University – sequence: 7 givenname: Si‐Dian orcidid: 0000-0001-5666-0591 surname: Li fullname: Li, Si‐Dian email: lisidian@sxu.edu.cn organization: Shanxi University |
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| Snippet | Based on detailed bonding analyses on the fluxional behaviors of planar B19−, tubular Ta@B20−, and cage‐like B39−, we propose the concept of fluxional bonds in... Based on detailed bonding analyses on the fluxional behaviors of planar B19 - , tubular Ta@B20 - , and cage-like B39 - , we propose the concept of fluxional... |
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| SubjectTerms | AdNDP bonding patterns Boron Cages Chemical bonds first‐principles theory fluxional bonds Organic chemistry structures |
| Title | Fluxional Bonds in Planar B19−, Tubular Ta@B20−, and Cage‐Like B39 |
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