Bending two-dimensional Cu(i)-based coordination networks to inverse electrocatalytic HER/CO2RR selectivity

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 12; no. 27; pp. 16396 - 16402
• Main Authors: Zheng, Kai, Ding-Yi, Hu, Xue-Wen, Zhang, Xian-Xian Xiao, Zi-Jun, Liang, Jun-Xi, Wu, Duo-Yu, Lin, Lin-Ling, Zhuo, Heng, Yi, Gong, Li, Dong-Dong, Zhou, Jie-Peng, Zhang
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 09.07.2024
• Subjects: Amino groups; Bending; Catalysis; Coordination polymers; Hydrogen bonding; Intermediates; Polymers; Reaction intermediates; Steric hindrance

Two-dimensional (2D) coordination polymers have attracted great attention for catalysis because of their abundant exposed active sites. Here, we show that bending the local structure of 2D coordination polymers can inverse the electrocatalytic selectivity. A series of ultrathin nanosheets based on i...