HIGH-OXIDATION-STATE PENTAMETHYLCYCLOPENTADIENYL TUNGSTEN HYDRAZINE AND HYDRAZIDO COMPLEXES AND CLEAVAGE OF THE N-N BOND - SCHROCK, RR; GLASSMAN, TE; VALE, MG; KOL, M (Journal of the American Chemical Society, 1993)
Keywords: Chemistry; Chemistry, Multidisciplinary; Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; Organic chemistry; Organic compounds; Organometalloidal and organometallic compounds; Physical Sciences; Physics; Preparations and properties; Science & Technology; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Transition metals derivatives; NITROGEN-FIXATION; NITRIDO COMPLEXES; ELECTRON-TRANSFER; CATALYTIC REDUCTION; MOLECULAR NITROGEN; COORDINATED DINITROGEN; MONO(DINITROGEN) COMPLEXES; DIHYDRIDE COMPLEXES; IRON MOLYBDENUM COFACTOR; AZOTOBACTER-VINELANDII; Cationic complex; Catalytic reaction; Amido complex; Organic ligand; Tungsten Organic compounds; Transition metal Complexes; Tetravalent metal Complexes; Ammino complex; Organic hydrazine; Scission; Chemical reduction; Ammonia; Pentavalent metal Complexes; Tungsten V Complexes; Tungsten IV Complexes; Imido complex; Reaction mechanism; Protonation; Hapto complex; Hydrazido complex; Hydrazine; Deprotonation