2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate

In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bond...

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Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. Pt 5; pp. o791 - o792
Main Authors Zhou, Chun-Shan, Huang, Xue-Ying, Meng, Xiang-Gao
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 02.04.2008
Subjects
Organic Papers
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Summary:In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808008519