Nickel(II) hexamethyleneiminedithiocarbamate complexes with triphenylphosphine or tributylphosphine

A series of square-planar nickel(II) hexamethylenedithiocarbamate complexes with heterogeneous coordination spheres of composition [NiX(hmidtc)Y] · nCHCl^sub 3^ [X = Cl, Br, I or NCS; hmi = C^sub 6^H^sub 12^, dtc = S^sub 2^CN^sup -^; Y = PPh^sub 3^ or PBu^sub 3^, n = 0,1] have been synthesized and c...

Full description

Saved in:
Bibliographic Details
Published inTransition metal chemistry (Weinheim) Vol. 28; no. 3; p. 260
Main Authors Pavlícek, Marek, Trávnícek, Zdenk, Pastorek, Richard, Marek, Jaromír
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Nature B.V 01.04.2003
Subjects
Nickel
Online AccessGet full text

Cover

More Information
Summary:A series of square-planar nickel(II) hexamethylenedithiocarbamate complexes with heterogeneous coordination spheres of composition [NiX(hmidtc)Y] · nCHCl^sub 3^ [X = Cl, Br, I or NCS; hmi = C^sub 6^H^sub 12^, dtc = S^sub 2^CN^sup -^; Y = PPh^sub 3^ or PBu^sub 3^, n = 0,1] have been synthesized and characterized by elemental analyses, i.r. and u.v.-v.i.s. spectroscopy, magnetochemical and conductivity measurements, and by thermal analysis. X-ray structures of [NiCl(hmidtc)(PPh^sub 3^)] · CHCl^sub 3^ and [NiBr(hmidtc)(PPh^sub 3^)] · CHCl^sub 3^ have been determined.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1023/A:1022932706275