Air-stable n-type colloidal quantum dot solids

Colloidal quantum dots (CQDs) offer promise in flexible electronics, light sensing and energy conversion. These applications rely on rectifying junctions that require the creation of high-quality CQD solids that are controllably n-type (electron-rich) or p-type (hole-rich). Unfortunately, n-type sem...

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Published inNature materials Vol. 13; no. 8; pp. 822 - 828
Main Authors Ning, Zhijun, Voznyy, Oleksandr, Pan, Jun, Hoogland, Sjoerd, Adinolfi, Valerio, Xu, Jixian, Li, Min, Kirmani, Ahmad R., Sun, Jon-Paul, Minor, James, Kemp, Kyle W., Dong, Haopeng, Rollny, Lisa, Labelle, André, Carey, Graham, Sutherland, Brandon, Hill, Ian, Amassian, Aram, Liu, Huan, Tang, Jiang, Bakr, Osman M., Sargent, Edward H.
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 01.08.2014
Nature Publishing Group
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Summary:Colloidal quantum dots (CQDs) offer promise in flexible electronics, light sensing and energy conversion. These applications rely on rectifying junctions that require the creation of high-quality CQD solids that are controllably n-type (electron-rich) or p-type (hole-rich). Unfortunately, n-type semiconductors made using soft matter are notoriously prone to oxidation within minutes of air exposure. Here we report high-performance, air-stable n-type CQD solids. Using density functional theory we identify inorganic passivants that bind strongly to the CQD surface and repel oxidative attack. A materials processing strategy that wards off strong protic attack by polar solvents enabled the synthesis of an air-stable n-type PbS CQD solid. This material was used to build an air-processed inverted quantum junction device, which shows the highest current density from any CQD solar cell and a solar power conversion efficiency as high as 8%. We also feature the n-type CQD solid in the rapid, sensitive, and specific detection of atmospheric NO 2 . This work paves the way for new families of electronic devices that leverage air-stable quantum-tuned materials. Although several techniques have been reported to obtain electron-rich colloidal quantum dots, these materials usually suffer from poor stability under air exposure. It is now shown that the use of strongly bound ligands and a careful ligands-exchange strategy lead to air-stable n-type quantum dots that can be used in solar cells and chemical sensors.
ISSN:1476-1122
1476-4660
DOI:10.1038/nmat4007