A MOF@MOF S-scheme Heterojunction with Lewis Acid-Base Sites Synergistically Boosts Cocatalyst-Free CO2 Cycloaddition

• Published in: ChemSusChem p. e202401362
• Main Authors: Shen, Qiuyan, Chen, Weiren, Wang, Min, Jin, Xixiong, Zhang, Lingxia, Shi, Jianlin
• Format: Journal Article
• Language: English
• Published: Germany 20.08.2024
• Subjects: Metal-organic frameworks, heterojunction, CO2 cycloaddition, Lewis sites, synergetic effect

The photocatalytic cycloaddition reaction between CO2 and epoxide is one of the most promising green routes for CO2 utilization, for which high performance photocatalysts are intensely desired. Herein, we have constructed an S-scheme heterojunction of MIL-125@ZIF-67 modified by amino groups, which a...