Ribonucleoside transformations. Synthesis of purine and pyrimidine nucleosides containing a fused cyclopropane ring
Fused cyclopropano keto nucleosides were synthesized by the beta-elimination and/or deoxygenative 1,2-hydride shift of mesylated ribonucleosides followed by the cyclopropanation of the resulting 3'-deoxy-2'-keto-5'-mesylated intermediates in a one-pot manner. The configurations of the...
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| Published in | Nucleic acids symposium series (1979) no. 25; pp. 93 - 94 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
England
1991
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Fused cyclopropano keto nucleosides were synthesized by the beta-elimination and/or deoxygenative 1,2-hydride shift of mesylated ribonucleosides followed by the cyclopropanation of the resulting 3'-deoxy-2'-keto-5'-mesylated intermediates in a one-pot manner. The configurations of the cyclopropano nucleosides were determined on the basis of their NOEs. |
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| AbstractList | Fused cyclopropano keto nucleosides were synthesized by the beta-elimination and/or deoxygenative 1,2-hydride shift of mesylated ribonucleosides followed by the cyclopropanation of the resulting 3'-deoxy-2'-keto-5'-mesylated intermediates in a one-pot manner. The configurations of the cyclopropano nucleosides were determined on the basis of their NOEs. |
| Author | Kawana, M Kuzuhara, H |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/1842112$$D View this record in MEDLINE/PubMed |
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| Snippet | Fused cyclopropano keto nucleosides were synthesized by the beta-elimination and/or deoxygenative 1,2-hydride shift of mesylated ribonucleosides followed by... |
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| SubjectTerms | Cyclopropanes - chemistry Magnetic Resonance Spectroscopy Molecular Structure Purines - chemical synthesis Purines - chemistry Pyrimidines - chemical synthesis Pyrimidines - chemistry Ribonucleosides - chemical synthesis Ribonucleosides - chemistry |
| Title | Ribonucleoside transformations. Synthesis of purine and pyrimidine nucleosides containing a fused cyclopropane ring |
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