Allylation and propargylation of aldehydes mediated by in situ generated zinc from the redox couple of Al and ZnCl2 in 2N HCl
A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which is in situ generated from the redox couple of Al and ZnCl2 in 2N HCl, is demonstrated to afford the corresponding homoallyl and homopropargyl alcohols with excellent yields.
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| Published in | New journal of chemistry Vol. 45; no. 16; pp. 7163 - 7173 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Royal Soc Chemistry
28.04.2021
Royal Society of Chemistry |
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| Abstract | A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which is in situ generated from the redox couple of Al and ZnCl2 in 2N HCl, is demonstrated to afford the corresponding homoallyl and homopropargyl alcohols with excellent yields. |
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| AbstractList | A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which is in situ generated from the redox couple of Al and ZnCl2 in 2N HCl, is demonstrated to afford the corresponding homoallyl and homopropargyl alcohols with excellent yields. |
| Author | Roy, Ujjal Kanti Hajra, Partha Pratim Mondal, Bibhas Adhikari, Utpal |
| Author_xml | – sequence: 1 givenname: Bibhas surname: Mondal fullname: Mondal, Bibhas organization: Kazi Nazrul Univ, Dept Chem, Asansol 713340, W Bengal, India – sequence: 2 givenname: Utpal surname: Adhikari fullname: Adhikari, Utpal organization: Natl Inst Technol Durgapur, Dept Chem, Durgapur 713209, India – sequence: 3 givenname: Partha Pratim surname: Hajra fullname: Hajra, Partha Pratim organization: Kazi Nazrul Univ, Dept Chem, Asansol 713340, W Bengal, India – sequence: 4 givenname: Ujjal Kanti orcidid: 0000-0001-7567-8762 surname: Roy fullname: Roy, Ujjal Kanti email: uroccu@gmail.com organization: Kazi Nazrul Univ, Dept Chem, Asansol 713340, W Bengal, India |
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| Cites_doi | 10.1021/jo400080y 10.1021/ol0064563 10.1021/acs.joc.5b01978 10.3184/174751911X13166274023054 10.1021/om700605y 10.1021/ol026619i 10.1021/ol0257326 10.1021/ol200043n 10.1016/j.tet.2009.08.051 10.1021/ol0493352 10.1039/c1ob06071f 10.1021/ja0274047 10.1021/cr020050h 10.1021/cr000003u 10.1016/j.jorganchem.2004.12.008 10.1021/ja071380s 10.1002/anie.201002751 10.1055/s-2005-872178 10.1021/ja016017e 10.1016/j.tet.2005.10.005 10.1039/c4qo00235k 10.1021/acs.orglett.5b03045 10.1021/jo015904x 10.1021/ol902457m |
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| Keywords | HALIDES KETONES TETRAPROPARGYLIC STANNANES TRANSMETALATION AQUEOUS-MEDIA HOMOALLYLIC ALCOHOLS CARBONYL ALLYLATION REACTIVITY EFFICIENT SOLVENT |
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| Snippet | A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which is in situ generated from the redox couple of Al and ZnCl2 in 2N HCl, is... |
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| SubjectTerms | Alcohols Aldehydes Allyl compounds Chemical reactions Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology Zinc chloride |
| Title | Allylation and propargylation of aldehydes mediated by in situ generated zinc from the redox couple of Al and ZnCl2 in 2N HCl |
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