Surface active ionic liquid assisted metal-free electrocatalytic-carboxylation in aqueous phase: a sustainable approach for CO2 utilization paired with electro-detoxification of halocarbons

• Published in: Green chemistry : an international journal and green chemistry resource : GC Vol. 23; no. 24; pp. 9992 - 10005
• Main Authors: Sarwar Ahmad Pandit, Sajad Ahmad Bhat, Mudasir Ahmad Rather, Feroz Ahmad Sofi, Ingole, Pravin P, Zahid Manzoor Bhat, Thotiyl, Musthafa Ottakam, Khursheed Ahmad Bhat, Rehman, Shakeel U, Mohsin Ahmad Bhat
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 13.12.2021
• Subjects: Aqueous electrolytes; Aqueous solutions; Buffers; Carbon dioxide; Carbon dioxide fixation; Carboxylation; Carboxylic acids; Detoxification; Electrochemistry; Electrodes; Electrolytes; Fixation; Green chemistry; Halocarbons; Intermediates; Ionic liquids; Ions; Micelles; Pollutants; Sails; Solubility; Water pollution

Electrocarboxylation of halocarbons is a promising green synthetic strategy for capture, fixation and utilization of CO2 for the synthesis of high-added-value industrial compounds. However, the unparalleled kinetic/thermodynamic stability and solubility concerns of CO2 and halocarbons warrant the us...