Diiron Azamonothiolates via Scission of Dithiadiazacyclooctanes by Iron Carbonyls

The reaction of Fe (CO) with the dithiadiazacyclooctanes [SCH N(R)CH ] affords Fe [SCH N(Me)CH ](CO) (R = Me, Bn). The methyl derivative was characterized crystallographically (Fe-Fe = 2.5702(5) Å). Its low symmetry is verified by variable temperature C NMR spectroscopy which revealed that the turns...

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Bibliographic Details
Published inEuropean journal of inorganic chemistry Vol. 2015; no. 25; pp. 4109 - 4114
Main Authors Lin, Tai, Ulloa, Olbelina A, Rauchfuss, Thomas B, Gray, Danielle L
Format Journal Article
LanguageEnglish
Published Germany 01.09.2014
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