Solvent-mediated secondary building units (SBUs) diversification in a series of Mn{sup II}-based metal-organic frameworks (MOFs)

• Published in: Journal of solid state chemistry Vol. 241
• Main Authors: Niu, Yan-Fei, Cui, Li-Ting, Han, Jie, Zhao, Xiao-Li, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002
• Format: Journal Article
• Language: English
• Published: United States 15.09.2016
• Subjects: CARBON DIOXIDE; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; LAYERS; LIGANDS; MONOCRYSTALS; ORGANOMETALLIC COMPOUNDS; PHOTOLUMINESCENCE; POLYMERS; POWDERS; PYRIDINE; SOLVENTS; STABILITY; WATER; X RADIATION; X-RAY DIFFRACTION

The role of auxiliary solvents in the formation of MOFs has been investigated for a series of Mn{sup II}-based framework systems. Reactions of 4,4′,4″-nitrilotribenzoic acid (H{sub 3}L) with Mn{sup II} through varying auxiliary solvents of the medium resulted in the formation of diversified multinuc...