熔融 LaCl3 - LiCl 2성분계 혼합염의 電導度

Electric Conductivities of LaCl3-LiCl binary melts have been measured by the Kohlausch bridge method over the range of their liquidus temperatures to about 1200K. The electric conductivity increases with the content of LiCl for all over the composition range of binary melts. Composition dependence o...

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Published in한국표면공학회지, 37(5) pp. 301 - 306
Main Author 김기호
Format Journal Article
LanguageKorean
Published 한국표면공학회 01.10.2004
Subjects
기계공학
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ISSN1225-8024
2288-8403

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Abstract Electric Conductivities of LaCl3-LiCl binary melts have been measured by the Kohlausch bridge method over the range of their liquidus temperatures to about 1200K. The electric conductivity increases with the content of LiCl for all over the composition range of binary melts. Composition dependence of the electric conductivity and molar conductivity for the binary melt shows a non-linear relation from the additivity line, and the deviations displays a maximum value at about 60mol % LiCl. This suggest the existence of the complex ion of LaCl4- in the melt. Activation energy for electric conductivity of the binary melts decrease monotonously with increasing content of LiCl. KCI Citation Count: 1
AbstractList Electric Conductivities of LaCl3-LiCl binary melts have been measured by the Kohlausch bridge method over the range of their liquidus temperatures to about 1200K. The electric conductivity increases with the content of LiCl for all over the composition range of binary melts. Composition dependence of the electric conductivity and molar conductivity for the binary melt shows a non-linear relation from the additivity line, and the deviations displays a maximum value at about 60mol % LiCl. This suggest the existence of the complex ion of LaCl4- in the melt. Activation energy for electric conductivity of the binary melts decrease monotonously with increasing content of LiCl. KCI Citation Count: 1
Author 김기호
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Title 熔融 LaCl3 - LiCl 2성분계 혼합염의 電導度
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