放射光小角X線散乱法による線状・環状・分岐高分子の溶液中における分子形態および分子間相互作用の研究
近年の放射光技術の進展に伴い，従来の光散乱法では測定が困難であった低温・高粘性率溶媒などの条件でも，小角X線散乱法により高分子希薄溶液物性を高精度に決定できるようになってきた．この手法は，高分子の剛直性がとくに重要になる比較的分子量が低い領域における環状・分岐高分子の分子形態決定にも重要な役割を果たす．本報では前者の特殊条件下での線状高分子の測定例として，広い温度範囲にわたるポリスチレンの特性比，低温でサーモクロミズム現象を示すポリシランの分子形態と分子間相互作用の温度変化，そしてレオロジー測定に適したイオン液体などの高粘性液体中における多糖類の分子形態の決定について，その手法とともに紹介する...
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| Published in | Kōbunshi ronbunshū (Tokyo) Vol. 75; no. 3; pp. 254 - 264 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
Tokyo
公益社団法人 高分子学会
25.05.2018
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0386-2186 1881-5685 |
| DOI | 10.1295/koron.2017-0088 |
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| Abstract | 近年の放射光技術の進展に伴い，従来の光散乱法では測定が困難であった低温・高粘性率溶媒などの条件でも，小角X線散乱法により高分子希薄溶液物性を高精度に決定できるようになってきた．この手法は，高分子の剛直性がとくに重要になる比較的分子量が低い領域における環状・分岐高分子の分子形態決定にも重要な役割を果たす．本報では前者の特殊条件下での線状高分子の測定例として，広い温度範囲にわたるポリスチレンの特性比，低温でサーモクロミズム現象を示すポリシランの分子形態と分子間相互作用の温度変化，そしてレオロジー測定に適したイオン液体などの高粘性液体中における多糖類の分子形態の決定について，その手法とともに紹介する．さらに，後者の非線状鎖の例として剛直な環状多糖誘導体，星形鎖，そして櫛形構造をもつ高分子電解質–棒状ペプチド複合体の分子形態の決定についてまとめる． |
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| AbstractList | 近年の放射光技術の進展に伴い，従来の光散乱法では測定が困難であった低温・高粘性率溶媒などの条件でも，小角X線散乱法により高分子希薄溶液物性を高精度に決定できるようになってきた．この手法は，高分子の剛直性がとくに重要になる比較的分子量が低い領域における環状・分岐高分子の分子形態決定にも重要な役割を果たす．本報では前者の特殊条件下での線状高分子の測定例として，広い温度範囲にわたるポリスチレンの特性比，低温でサーモクロミズム現象を示すポリシランの分子形態と分子間相互作用の温度変化，そしてレオロジー測定に適したイオン液体などの高粘性液体中における多糖類の分子形態の決定について，その手法とともに紹介する．さらに，後者の非線状鎖の例として剛直な環状多糖誘導体，星形鎖，そして櫛形構造をもつ高分子電解質–棒状ペプチド複合体の分子形態の決定についてまとめる． Recent developments of synchrotron-radiation small-angle X-ray scattering (SAXS) measurements for dilute polymer solution make it possible to determine dimensional properties and intermolecular interactions quantitatively even in common organic solvents at very low temperatures, and in viscous solvents. This paper reports these characteristics for polystyrene in two solvents at a wide temperature range, molecular conformation and intermolecular interactions for thermochromic polysilanes, and conformational properties of polysaccharides in high viscous solvents including an ionic liquid. This method can also be applied to solutions of cyclic and branched polymers with relatively low molar mass, and we describe dilute solution properties of rigid cyclic polysaccharide derivatives, semiflexible and rigid star polymers, and comb-like complexes of polyelectrolytes and rigid helical polypeptides. |
| Author | 長谷川, 博一 領木, 研之 蒋, 昕悦 寺尾, 憲 |
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| Snippet | ... Recent developments of synchrotron-radiation small-angle X-ray scattering (SAXS) measurements for dilute polymer solution make it possible to determine... |
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| SubjectTerms | Dilution Hydrogen bonds Ionic liquids Molecular chains Molecular conformation Polyelectrolytes Polymers Polypeptides Polysaccharides Polysilanes Polystyrene resins Properties (attributes) Small angle X ray scattering Solvents |
| Title | 放射光小角X線散乱法による線状・環状・分岐高分子の溶液中における分子形態および分子間相互作用の研究 |
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