Highly sensitive and selective fluorescent chemosensor for Ag+ based on a coumarin-Se2N chelating conjugate
A highly sensitive and selective fluorescent chemosensor SC1 for Ag+ based on a coumarin-Se2N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the bindi...
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Published in | Chemical communications (Cambridge, England) Vol. 47; no. 8; pp. 2408 - 2410 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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Royal Soc Chemistry
01.01.2011
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Abstract | A highly sensitive and selective fluorescent chemosensor SC1 for Ag+ based on a coumarin-Se2N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag+ cation to the chemosensor SC1 with a detection limit down to the 10(-8) M range. |
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AbstractList | A highly sensitive and selective fluorescent chemosensor SC1 for Ag+ based on a coumarin-Se2N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag+ cation to the chemosensor SC1 with a detection limit down to the 10(-8) M range. A highly sensitive and selective fluorescent chemosensor SC1 for Ag⁺ based on a coumarin–Se₂N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag⁺ cation to the chemosensor SC1 with a detection limit down to the 10⁻⁸ M range. A highly sensitive and selective fluorescent chemosensor SC1 for Ag(+) based on a coumarin-Se(2)N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag(+) cation to the chemosensor SC1 with a detection limit down to the 10(-8) M range. A highly sensitive and selective fluorescent chemosensor SC1 for Ag(+) based on a coumarin-Se(2)N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag(+) cation to the chemosensor SC1 with a detection limit down to the 10(-8) M range.A highly sensitive and selective fluorescent chemosensor SC1 for Ag(+) based on a coumarin-Se(2)N chelating conjugate has been synthesized and characterized. Due to inhibiting a photoinduced electron transfer (PET) quenching pathway, a fluorescent enhancement factor of 4-fold is observed under the binding of the Ag(+) cation to the chemosensor SC1 with a detection limit down to the 10(-8) M range. |
Author | Wei, Fangfang Zeng, Xianshun Lu, Yan Huang, Shanshan Zhao, Liancheng He, Song |
Author_xml | – sequence: 1 givenname: Shanshan surname: Huang fullname: Huang, Shanshan organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China – sequence: 2 givenname: Song surname: He fullname: He, Song organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China – sequence: 3 givenname: Yan surname: Lu fullname: Lu, Yan email: luyan@tjut.edu.cn organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China – sequence: 4 givenname: Fangfang surname: Wei fullname: Wei, Fangfang organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China – sequence: 5 givenname: Xianshun surname: Zeng fullname: Zeng, Xianshun email: xshzeng@tjut.edu.cn organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China – sequence: 6 givenname: Liancheng orcidid: 0000-0002-1414-3454 surname: Zhao fullname: Zhao, Liancheng email: lczhao@hit.edu.cn organization: Tianjin Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/21165497$$D View this record in MEDLINE/PubMed |
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Keywords | SILVER ION RECOGNITION ESCHERICHIA-COLI SENSOR MOLECULES ELECTRODE ADENINE RECEPTORS DERIVATIVES NEUTRAL CARRIER AQUEOUS-SOLUTION |
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Snippet | A highly sensitive and selective fluorescent chemosensor SC1 for Ag+ based on a coumarin-Se2N chelating conjugate has been synthesized and characterized. Due... A highly sensitive and selective fluorescent chemosensor SC1 for Ag(+) based on a coumarin-Se(2)N chelating conjugate has been synthesized and characterized.... A highly sensitive and selective fluorescent chemosensor SC1 for Ag⁺ based on a coumarin–Se₂N chelating conjugate has been synthesized and characterized. Due... |
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SubjectTerms | Binding Cations Chelating Chelating Agents - chemistry chemical communication Chemistry Chemistry, Multidisciplinary Conjugates Coumarins - chemical synthesis Coumarins - chemistry detection limit Electron transfer Electron Transport fluorescence Organoselenium Compounds - chemical synthesis Organoselenium Compounds - chemistry Pathways Physical Sciences Quenching Science & Technology Selenium - chemistry silver Silver - analysis Spectrometry, Fluorescence - methods Tomography |
Title | Highly sensitive and selective fluorescent chemosensor for Ag+ based on a coumarin-Se2N chelating conjugate |
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