Single‐crystal structure refinements and Debye temperatures of Ir2S3 kashinite and Rh2S3 bowieite

• Published in: Acta crystallographica. Section C, Crystal structure communications Vol. 78; no. 11; pp. 606 - 611
• Main Authors: Yoshiasa, Akira, Kitahara, Ginga, Tokuda, Makoto, Ishimaru, Satoko, Ono, Shin-ichiro, Terai, Kunihisa, Nakatsuka, Akihiko, Sugiyama, Kazumasa
• Format: Journal Article
• Language: English
• Published: Chester Wiley Subscription Services, Inc 01.11.2022
• Subjects: Chemical bonds; Chemical transport; Crystal structure; Crystallization; Crystals; Debye temperature; Earth mantle; Iron sulfides; Magma; Parameters; Rhodium compounds; Silica; Silica glass; Single crystals; Tubes

Single crystals of Ir2S3 (diiridium trisulfide) and Rh2S3 (dirhodium trisulfide) were grown in evacuated silica‐glass tubes using a chemical transport method and their crystal structures were determined by single‐crystal X‐ray diffraction analysis. These compounds have a unique sesquisulfide structu...