Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy

Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.

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Published inBulletin of the Korean Chemical Society Vol. 41; no. 10; pp. 966 - 968
Main Authors Park, Seongchul, Shin, Juhyang, Yoon, Hojeong, Lim, Manho
Format Journal Article
LanguageEnglish
Published Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.10.2020
대한화학회
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Online AccessGet full text
ISSN1229-5949
0253-2964
1229-5949
DOI10.1002/bkcs.12096

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Abstract Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.
AbstractList Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4. KCI Citation Count: 3
Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.
Author Shin, Juhyang
Yoon, Hojeong
Lim, Manho
Park, Seongchul
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Snippet Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately...
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SubjectTerms Geminate rebinding
isoHalomethane
Reaction in solution
Solvent cage
Solvent‐assisted reaction
Time‐resolved infrared spectroscopy
화학
Title Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fbkcs.12096
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