Enhanced C3H6/C3H8 separation performance on MOF membranes through blocking defects and hindering framework flexibility by silicone rubber coating

The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 55; pp. 7760 - 7763
Main Authors Sheng, Luqian, Wang, Chongqing, Yang, Fan, Xiang, Long, Huang, Xiaojian, Yu, Jian, Zhang, Lixiong, Pan, Yichang, Li, Yanshuo
Format Journal Article
LanguageEnglish
Published 06.07.2017
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Abstract The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3H6/C3H8 mixture under high feeding pressures.The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3H6/C3H8 mixture under high feeding pressures.
AbstractList The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C₃H₆/C₃H₈ mixture under high feeding pressures.
The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3H6/C3H8 mixture under high feeding pressures.The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3H6/C3H8 mixture under high feeding pressures.
Author Yu, Jian
Sheng, Luqian
Xiang, Long
Huang, Xiaojian
Li, Yanshuo
Yang, Fan
Wang, Chongqing
Pan, Yichang
Zhang, Lixiong
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Snippet The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also...
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SubjectTerms chemical reactions
coatings
polydimethylsiloxane
rubber
Title Enhanced C3H6/C3H8 separation performance on MOF membranes through blocking defects and hindering framework flexibility by silicone rubber coating
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