Centimeter-Scale Pillared-Layer Metal-Organic Framework Thin Films Mediated by Hydroxy Double Salt Intermediates for CO2 Sensor Applications

• Published in: ACS applied materials & interfaces Vol. 13; no. 1; pp. 2062 - 2071
• Main Authors: Kim, Ki-Joong, Ellis, James E, Howard, Bret H, Ohodnicki, Paul R
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society (ACS) 22.12.2020
• Subjects: ambient temperature; anisotropy; carbon dioxide; carbon dioxide sensing in humid conditions; coordination polymers; humidity; hydroxy double salts; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; large-scale pillared MOF thin films; layers; ligands; metal organic frameworks; optical fiber sensor; optical fibers; optics; quartz crystal microbalance; quartz crystal microbalance sensor; sensors; thin films; water solubility; zinc oxide
• ISSN: 1944-8252; 1944-8244; 1944-8252
• DOI: 10.1021/acsami.0c19621

Fabrication of metal-organic framework (MOF) thin films over macroscopic surface areas is a subject of great interest for gas sensor application platforms such as optics and microelectronics. However, a direct synthesis of MOF films at ambient conditions, in particular pillared-layer MOF films due t...