暴露試験による揮発性有機化合物用パッシブサンプラーのサンプリングレートに関する実験的評価
Recently, passive air sampling in indoor air monitoring of volatile organic compounds (VOCs) has received increasing attention, because it is easy to handling and low cost sampling method. However, in order to calculate concentration of each target VOCs, information of sampling rate (SR) is needed....
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| Published in | Journal of environmental chemistry Vol. 26; no. 4; pp. 203 - 210 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | Japanese |
| Published |
Tsukuba
一般社団法人 日本環境化学会
01.01.2016
Japan Science and Technology Agency |
| Subjects | |
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| Abstract | Recently, passive air sampling in indoor air monitoring of volatile organic compounds (VOCs) has received increasing attention, because it is easy to handling and low cost sampling method. However, in order to calculate concentration of each target VOCs, information of sampling rate (SR) is needed. Therefore, one of the aims of this study is to establish the method convenient to obtain SR by exposure test which adopt a small and cost-effective exposure chamber. The result show that this approach was effective, because the sampling rate obtained are comparable with reference value and are reproducible result. Another aim is evaluations of effect of adsorbent and sampler case of passive air sampler to SR. The six passive air samplers consist two kinds of passive air sampler cases and three kinds of absorbents were exposed to VOCs for 24 hours and SR are determined. The results showed that sampler case and adsorbent affect the value of SR. |
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| AbstractList | Recently, passive air sampling in indoor air monitoring of volatile organic compounds (VOCs) has received increasing attention, because it is easy to handling and low cost sampling method. However, in order to calculate concentration of each target VOCs, information of sampling rate (SR) is needed. Therefore, one of the aims of this study is to establish the method convenient to obtain SR by exposure test which adopt a small and cost-effective exposure chamber. The result show that this approach was effective, because the sampling rate obtained are comparable with reference value and are reproducible result. Another aim is evaluations of effect of adsorbent and sampler case of passive air sampler to SR. The six passive air samplers consist two kinds of passive air sampler cases and three kinds of absorbents were exposed to VOCs for 24 hours and SR are determined. The results showed that sampler case and adsorbent affect the value of SR. |
| Author | 石坂, 閣啓 川嶋, 文人 |
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| References | 2) 厚生労働省医薬食品局「第18回シックハウス（室内空気汚染） 問題に関する検討会」（2014年3 月17日） 9) 光崎 純，中井里史，白砂裕一郎，平野耕一郎：拡散型サンプラーにおける理論的捕集速度の算出法の検討，室内環境学会誌， 9 ，1-9（2006） 8) 雨谷敬史，烏蘭参丹，松下秀鶴：パッシブサンプラーを用いた空気中有機ハロゲン化合物の簡易分析法，大気環境学会誌，31，191-202（1996） 1) 厚生労働省「シックハウス（室内空気汚染）問題に関する検討会中間報告書－第6 回～第7 回のまとめ」 12) Perez Ballesta, P., Gonzalez Ferradas, E. and Minana, A.: Effects of the diffusion membrane on passive sampling. Environ. Sci. Technol., 27, 2031-2034 (1993 5) Araki, A., Eitaki, Y., Kawai, T., Kanazawa, A., Takeda, M. and Kishi, R.: Diffusive sampling and measurement of microbial volatile organic compounds in indoor air. Indoor Air., 19, 421-432 (2009 15) 関根嘉香，廣田ちはる，佛願道男：空気中揮発性有機化合物（VOCs）濃度測定用溶媒脱離型パッシブサンプラーの性能評価，環境化学，12，847-854（2002） 13) Bates, M., Gonzalez-Flesca, N., Cocheo, V. and Sokhi, R.: Ambient volatile organic compound monitoring by diffusive sampling. compatibility of high uptake rate samplers with thermal desorption. Analyst, 122, 1481-1484 (1997 3) 斎藤育江，大貫 文，戸高恵美子，中岡宏子，森 千里，保坂 三継，小縣昭夫：近年の室内空気汚染問題について：未規制物質による健康リスク，日本リスク研究学会誌,21，91-100（2011） 6) JIS A 1968：2015. 室内空気中の揮発性有機化合物（VOC）の 吸着捕集・溶媒抽出・キャピラリーガスクロマトグラフィーによるサンプリング及び分析－ポンプサンプリング 14) Sekine, Y., Watts, S.F., Rendell, A. and Butsugan, M.: Development of highly sensitive passive sampler for nitrogen dioxide using porous polyethylene membrane filter as turbulence limiting diffuser. Atmospheric Environment, 42, 4079-4088 (2008 4) 香川（田中）聡子，神野透人，小濱とも子，西村哲治，徳永裕司：ハンドスプレー式家庭用品から放散する揮発性有機化合物に関する研究，国立衛研報，126，88-92（2008） 10) Pennequin-Cardinal, A., Plaisance, H., Locoge, N., Ramalho, O., Kirchner, S. and Galloo, J.C.: Performances of the radiellos diffusive sampler for BTEX measurements influence of environmental conditions and determination of modelled sampling rates. Atmospheric Environment, 39, 2535-2544 (2005 11) ISO 16107:2007 Workplace atmospheres - Protocol for evaluating the performance of diffusive samplers 7) JIS A 1969：2015室内空気中の揮発性有機化合物（VOC）の吸着捕集・溶媒抽出・キャピラリーガスクロマトグラフィーによるサンプリング及び分析－パッシブサンプリング |
| References_xml | – reference: 9) 光崎 純，中井里史，白砂裕一郎，平野耕一郎：拡散型サンプラーにおける理論的捕集速度の算出法の検討，室内環境学会誌， 9 ，1-9（2006） – reference: 13) Bates, M., Gonzalez-Flesca, N., Cocheo, V. and Sokhi, R.: Ambient volatile organic compound monitoring by diffusive sampling. compatibility of high uptake rate samplers with thermal desorption. Analyst, 122, 1481-1484 (1997) – reference: 4) 香川（田中）聡子，神野透人，小濱とも子，西村哲治，徳永裕司：ハンドスプレー式家庭用品から放散する揮発性有機化合物に関する研究，国立衛研報，126，88-92（2008） – reference: 7) JIS A 1969：2015室内空気中の揮発性有機化合物（VOC）の吸着捕集・溶媒抽出・キャピラリーガスクロマトグラフィーによるサンプリング及び分析－パッシブサンプリング – reference: 6) JIS A 1968：2015. 室内空気中の揮発性有機化合物（VOC）の 吸着捕集・溶媒抽出・キャピラリーガスクロマトグラフィーによるサンプリング及び分析－ポンプサンプリング – reference: 11) ISO 16107:2007 Workplace atmospheres - Protocol for evaluating the performance of diffusive samplers – reference: 14) Sekine, Y., Watts, S.F., Rendell, A. and Butsugan, M.: Development of highly sensitive passive sampler for nitrogen dioxide using porous polyethylene membrane filter as turbulence limiting diffuser. Atmospheric Environment, 42, 4079-4088 (2008) – reference: 12) Perez Ballesta, P., Gonzalez Ferradas, E. and Minana, A.: Effects of the diffusion membrane on passive sampling. Environ. Sci. Technol., 27, 2031-2034 (1993) – reference: 15) 関根嘉香，廣田ちはる，佛願道男：空気中揮発性有機化合物（VOCs）濃度測定用溶媒脱離型パッシブサンプラーの性能評価，環境化学，12，847-854（2002） – reference: 3) 斎藤育江，大貫 文，戸高恵美子，中岡宏子，森 千里，保坂 三継，小縣昭夫：近年の室内空気汚染問題について：未規制物質による健康リスク，日本リスク研究学会誌,21，91-100（2011） – reference: 1) 厚生労働省「シックハウス（室内空気汚染）問題に関する検討会中間報告書－第6 回～第7 回のまとめ」 – reference: 10) Pennequin-Cardinal, A., Plaisance, H., Locoge, N., Ramalho, O., Kirchner, S. and Galloo, J.C.: Performances of the radiellos diffusive sampler for BTEX measurements influence of environmental conditions and determination of modelled sampling rates. Atmospheric Environment, 39, 2535-2544 (2005) – reference: 8) 雨谷敬史，烏蘭参丹，松下秀鶴：パッシブサンプラーを用いた空気中有機ハロゲン化合物の簡易分析法，大気環境学会誌，31，191-202（1996） – reference: 5) Araki, A., Eitaki, Y., Kawai, T., Kanazawa, A., Takeda, M. and Kishi, R.: Diffusive sampling and measurement of microbial volatile organic compounds in indoor air. Indoor Air., 19, 421-432 (2009) – reference: 2) 厚生労働省医薬食品局「第18回シックハウス（室内空気汚染） 問題に関する検討会」（2014年3 月17日） |
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| SubjectTerms | Adsorbents Air monitoring Air sampling Exposure Indoor environments Organic compounds Samplers VOCs Volatile organic compounds |
| Title | 暴露試験による揮発性有機化合物用パッシブサンプラーのサンプリングレートに関する実験的評価 |
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