キラルイオン性ラジカル液晶の合成と磁性

To investigate whether the local structure of ionic liquids is similar to the domain structure of liquid crystals, we have designed and synthesized two sets of racemic and S,S-enriched ionic liquid crystalline compounds which can show the achiral and chiral smectic A (SmA) phases, respectively, and...

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Published inProceedings of Japanese Liquid Crystal Society Annual meeting Vol. 2016; p. PA04
Main Authors 内田, 幸明, 武元, 佑紗, 三浦, 篤史, 坂口, 辰徳, 下野, 智史, 田村, 類, 加藤, 立久
Format Journal Article
LanguageJapanese
Published 一般社団法人 日本液晶学会 2016
THE JAPANESE LIQUID CRYSTAL SOCIETY
Online AccessGet full text
ISSN1880-3490
2432-5988
DOI10.11538/ekitou.2016.0_PA04

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Abstract To investigate whether the local structure of ionic liquids is similar to the domain structure of liquid crystals, we have designed and synthesized two sets of racemic and S,S-enriched ionic liquid crystalline compounds which can show the achiral and chiral smectic A (SmA) phases, respectively, and characterized their magnetic properties by SQUID magnetometry and EPR spectroscopy. Here we report the experimental results on the comparison of temperature dependences of the molar magnetic susceptibility (χM), molecular orientation (g-value) and line width (ΔHpp) of the crystalline, LC, and isotropic phases.
AbstractList To investigate whether the local structure of ionic liquids is similar to the domain structure of liquid crystals, we have designed and synthesized two sets of racemic and S,S-enriched ionic liquid crystalline compounds which can show the achiral and chiral smectic A (SmA) phases, respectively, and characterized their magnetic properties by SQUID magnetometry and EPR spectroscopy. Here we report the experimental results on the comparison of temperature dependences of the molar magnetic susceptibility (χM), molecular orientation (g-value) and line width (ΔHpp) of the crystalline, LC, and isotropic phases.
Author 三浦, 篤史
武元, 佑紗
下野, 智史
加藤, 立久
田村, 類
内田, 幸明
坂口, 辰徳
Author_FL Miura Atsushi
Tamura Rui
Uchida Yoshiaki
Kato Tatsuhisa
Sakaguchi Tatsunori
Shimono Satoshi
Takemoto Yusa
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