Examination of Heating Media for a Metal Oxide Film to Create Materials for Teaching about Light Interference

The changing colors seen in soap bubbles or oil floating on water are the result of thin-film interference. These are not the actual colors of the substance itself, but are color changes brought about by its structure. They are a familiar sight to children and, as a subject for study, they can excit...

Full description

Saved in:
Bibliographic Details
Published inTransactions on GIGAKU Vol. 9; no. 2; pp. 09015-1 - 09015-9
Main Authors Ueno, Takahisa, Ninomiya, Junko, Tomiyoshi, Ryota, Hinago, Kaname
Format Journal Article
LanguageEnglish
Published Nagaoka University of Technology 29.07.2022
国立大学法人 長岡技術科学大学
Online AccessGet full text

Cover

Loading…
Abstract The changing colors seen in soap bubbles or oil floating on water are the result of thin-film interference. These are not the actual colors of the substance itself, but are color changes brought about by its structure. They are a familiar sight to children and, as a subject for study, they can excite scientific curiosity while also being fun to observe. In practical science education, there have been reports of thin-film interference in metal oxide films produced by the anodic oxidation of titanium being used for the development of teaching materials or in teacher training seminars. However, anodic oxidation requires high voltages, and there is also a need to dispose of fluid waste (e.g., phosphoric acid aqueous solution). For this reason, there are few reports of this method being used in practical classes. Within the range of our survey, the interference and diffraction of light has been covered in high school physics classes using soap bubbles, but we found no reports of practical experiments using metal oxide films. Here, we show that after an Sn–Zn binary alloy (85:15 mol%) is heated to melting point, it oxidizes upon exposure to air and interference colors can be observed as a result. The melting point of the Sn–Zn binary alloy is low (198.5 ºC), such that the alloy can be melted using a microwave oven. Furthermore, if the oxide film that forms on the surface of the metal is removed by re-heating, the alloy can be used repeatedly for the experiment. Not only does this cut down the required preparation steps and fluid waste disposal, it also reduces the environmental burden, as the experimental material is reusable. It is theoretically possible to reproduce a given target interference color by adjusting the thickness of the metal oxide film. We compare the temperature characteristics of carbon powder and copper (II) oxide as heating media, in order to determine whether an oxide film can be reliably formed. As a result, we confirm that the oxide film could be formed in a shorter time when using copper (II) oxide as the heating medium.
AbstractList The changing colors seen in soap bubbles or oil floating on water are the result of thin-film interference. These are not the actual colors of the substance itself, but are color changes brought about by its structure. They are a familiar sight to children and, as a subject for study, they can excite scientific curiosity while also being fun to observe. In practical science education, there have been reports of thin-film interference in metal oxide films produced by the anodic oxidation of titanium being used for the development of teaching materials or in teacher training seminars. However, anodic oxidation requires high voltages, and there is also a need to dispose of fluid waste (e.g., phosphoric acid aqueous solution). For this reason, there are few reports of this method being used in practical classes. Within the range of our survey, the interference and diffraction of light has been covered in high school physics classes using soap bubbles, but we found no reports of practical experiments using metal oxide films. Here, we show that after an Sn–Zn binary alloy (85:15 mol%) is heated to melting point, it oxidizes upon exposure to air and interference colors can be observed as a result. The melting point of the Sn–Zn binary alloy is low (198.5 ºC), such that the alloy can be melted using a microwave oven. Furthermore, if the oxide film that forms on the surface of the metal is removed by re-heating, the alloy can be used repeatedly for the experiment. Not only does this cut down the required preparation steps and fluid waste disposal, it also reduces the environmental burden, as the experimental material is reusable. It is theoretically possible to reproduce a given target interference color by adjusting the thickness of the metal oxide film. We compare the temperature characteristics of carbon powder and copper (II) oxide as heating media, in order to determine whether an oxide film can be reliably formed. As a result, we confirm that the oxide film could be formed in a shorter time when using copper (II) oxide as the heating medium.
Author Ueno, Takahisa
Hinago, Kaname
Ninomiya, Junko
Tomiyoshi, Ryota
Author_xml – sequence: 1
  fullname: Ueno, Takahisa
– sequence: 1
  fullname: Ninomiya, Junko
  organization: General Education, National Institute of Technology, Oita College
– sequence: 1
  fullname: Tomiyoshi, Ryota
– sequence: 1
  fullname: Hinago, Kaname
BackLink https://cir.nii.ac.jp/crid/1390855886881795328$$DView record in CiNii
BookMark eNo9kE9PAjEQxRujiYh8Ai89eF3sn223PSoBIYFwwXMz3e0uRbZrumuC394CxsO8ecn85h3eA7oNXXAIPVEy5Xku1UvjG_j8nuopM0QTKjJ6g0Ys5yITSot7NOn7AyGEM14UTI1QOz9B6wMMvgu4q_HSJRsavHGVB1x3EUPyAxzx9uQrhxf-2OKhw7OYQIc3SaKHY39Bdw7K_fkbbPc94LVv9gNehYTULrpQukd0VyfYTf72GH0s5rvZMltv31ez13V2YJSqDBgRXGoiZVXUMi8rroGKSjkNzAkCmklrLTBlJbeilkxwW0kNlS2Bk5rxMXq-5gbvTenPSrkmSgilpFK00IIzlbC3K3boB2ic-Yq-hfhjIA6-PDpzLdNow9Jc6jT0_1juIRoX-C-963OK
ContentType Journal Article
Copyright 2022 Nagaoka University of Technology
Copyright_xml – notice: 2022 Nagaoka University of Technology
DBID RYH
DOI 10.34468/gigaku.9.2_09015-1
DatabaseName CiNii Complete
DatabaseTitleList

DeliveryMethod fulltext_linktorsrc
EISSN 2435-5895
EndPage 09015-9
ExternalDocumentID article_gigaku_9_2_9_09015_1_article_char_en
GroupedDBID ALMA_UNASSIGNED_HOLDINGS
JSF
JSH
M~E
RJT
RZJ
RYH
ID FETCH-LOGICAL-j2118-a205369066d7f64cd39a15d8e9a2e50a926bbba28b63b5f6253bd69adbca30f23
IngestDate Thu Jun 26 23:20:30 EDT 2025
Wed Sep 03 06:31:10 EDT 2025
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed false
IsScholarly false
Issue 2
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-j2118-a205369066d7f64cd39a15d8e9a2e50a926bbba28b63b5f6253bd69adbca30f23
OpenAccessLink https://www.jstage.jst.go.jp/article/gigaku/9/2/9_09015-1/_article/-char/en
ParticipantIDs nii_cinii_1390855886881795328
jstage_primary_article_gigaku_9_2_9_09015_1_article_char_en
PublicationCentury 2000
PublicationDate 2022/07/29
2022-07-29
PublicationDateYYYYMMDD 2022-07-29
PublicationDate_xml – month: 07
  year: 2022
  text: 2022/07/29
  day: 29
PublicationDecade 2020
PublicationTitle Transactions on GIGAKU
PublicationTitleAlternate gigaku
PublicationTitle_FL gigaku
Transactions on GIGAKU
PublicationYear 2022
Publisher Nagaoka University of Technology
国立大学法人 長岡技術科学大学
Publisher_xml – name: Nagaoka University of Technology
– name: 国立大学法人 長岡技術科学大学
References 5 [5] T.Hashiguchi and H.Sueyoshi, “Effect of atmosphere on microwave heating of titanium powder”, Powder Metallurgy, vol.54, no.4, pp.537-542, 2011.
3 [3] Japan Institute of Metals and Materials,“The Japan Institute of Metals Metal Data Book”, p.126, 2004.
9 [9] M.Samouhos, R.Hutcheon, I.Paspaliaris, “Microwave reduction of copper(II) oxide and malachite concentrate”, Minerals Engineering, vol.24, pp.903-913 Mar. 2011.
2 [2] T.Ueno, J.Ninomiya, T.Takahashi, H.Sato, “Use of Metallic Oxide Film Formed on the Sn-Zn Alloy as Educational Material about Light Interference”, IEEJ Transactions on Fundamentals and Materials, vol.137, no.7, pp.410-415, July, 2017.
1 [1] S.Fujita, “Casting of binary alloys using microwave oven”, Ehime Prefectural Museum of General Science Research Report, vol.8, pp.1-5, 2003.
8 [8] S.Sarkar, P.Jana, B.Chaudhuri and H.Sakata, H, “Copper (II) Oxide as a Giant Dielectric Material” Applied Physics Letters. vol.89, 2006.
7 [7] E.Binner et al., “A Review of Microwave Coal Processing”, Journal of Microwave Power and Electromagnetic Energy, vol.48, pp.35-60, 2013.
10 [10] A.O. Salohub, A.A. Voznyi, O.V. Klymov, N.V. Safryuk, D.I. Kurbatov, A.S. Opanasyuk, “ Determination of fundamental optical constants of Zn2SnO4 films”, Semiconductor Physics, Quantum Electronics & Optoelectronics, vol. 20, no.1, pp. 79-84, 2017.
4 [4]H.Liang, C.Masatoshi and W.Tohru, “Relationship between Crystallographic Structure of Electroplated Cu・Sn Alloy Film and Its Thermal Equilibrium Diagram”, Journal of Japan Institute of Metals and Materials,vo1.63, no.4, pp.474-48, 1999
6 [6] Q.Liu, B.Cao, C.Feng, W.Zhang, S.Zhu and S.Zhang, “High permittivity and microwave absorption of porous graphitic carbons encapsulating Fe nanoparticles”, Composites Science and Technology, vol.72, pp.1632–1636, June, 2012.
References_xml – reference: 7 [7] E.Binner et al., “A Review of Microwave Coal Processing”, Journal of Microwave Power and Electromagnetic Energy, vol.48, pp.35-60, 2013.
– reference: 3 [3] Japan Institute of Metals and Materials,“The Japan Institute of Metals Metal Data Book”, p.126, 2004.
– reference: 10 [10] A.O. Salohub, A.A. Voznyi, O.V. Klymov, N.V. Safryuk, D.I. Kurbatov, A.S. Opanasyuk, “ Determination of fundamental optical constants of Zn2SnO4 films”, Semiconductor Physics, Quantum Electronics & Optoelectronics, vol. 20, no.1, pp. 79-84, 2017.
– reference: 4 [4]H.Liang, C.Masatoshi and W.Tohru, “Relationship between Crystallographic Structure of Electroplated Cu・Sn Alloy Film and Its Thermal Equilibrium Diagram”, Journal of Japan Institute of Metals and Materials,vo1.63, no.4, pp.474-48, 1999
– reference: 9 [9] M.Samouhos, R.Hutcheon, I.Paspaliaris, “Microwave reduction of copper(II) oxide and malachite concentrate”, Minerals Engineering, vol.24, pp.903-913 Mar. 2011.
– reference: 1 [1] S.Fujita, “Casting of binary alloys using microwave oven”, Ehime Prefectural Museum of General Science Research Report, vol.8, pp.1-5, 2003.
– reference: 6 [6] Q.Liu, B.Cao, C.Feng, W.Zhang, S.Zhu and S.Zhang, “High permittivity and microwave absorption of porous graphitic carbons encapsulating Fe nanoparticles”, Composites Science and Technology, vol.72, pp.1632–1636, June, 2012.
– reference: 8 [8] S.Sarkar, P.Jana, B.Chaudhuri and H.Sakata, H, “Copper (II) Oxide as a Giant Dielectric Material” Applied Physics Letters. vol.89, 2006.
– reference: 2 [2] T.Ueno, J.Ninomiya, T.Takahashi, H.Sato, “Use of Metallic Oxide Film Formed on the Sn-Zn Alloy as Educational Material about Light Interference”, IEEJ Transactions on Fundamentals and Materials, vol.137, no.7, pp.410-415, July, 2017.
– reference: 5 [5] T.Hashiguchi and H.Sueyoshi, “Effect of atmosphere on microwave heating of titanium powder”, Powder Metallurgy, vol.54, no.4, pp.537-542, 2011.
SSID ssj0003237728
Score 1.8044815
Snippet The changing colors seen in soap bubbles or oil floating on water are the result of thin-film interference. These are not the actual colors of the substance...
SourceID nii
jstage
SourceType Publisher
StartPage 09015-1
Title Examination of Heating Media for a Metal Oxide Film to Create Materials for Teaching about Light Interference
URI https://www.jstage.jst.go.jp/article/gigaku/9/2/9_09015-1/_article/-char/en
https://cir.nii.ac.jp/crid/1390855886881795328
Volume 9
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
ispartofPNX Transactions on GIGAKU, 2022/07/29, Vol.9(2), pp.09015-1-09015-9
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3Nb9MwFLe6ceGChgAx2JAP3KqU1M6HLU7TtK18rEiolXaLnpO0ZGUJYqm0ceAv44_jPTtpsrEDg0OjyHXsNu-n59-z3wdjr40JYh3r3MtjEXgBZNozGSpD0n0qRW0Y2g2302k0mQfvz8KzweBXz2tpXZtR-uPOuJJ_kSq2oVwpSvYekt0Mig14j_LFK0oYr38l46MrIE-WlvRNiP-h5U-HL-DcI_Geoh0_XRVZPjwuvl4Q1zwkokg1h2r3I23XWetW6VyVP5LR7vYLm4jAPo2ddVXG7XHDybuTgw_zVnjz3NbzHs5gBV-Ky43inxYUA33tvHPX5arqtrixubq09YWHn6-revPIBP_esnJuHyU0iRWaTQphHVpFpwqnsIRqBbecTW4dHuRW6wnkb16oXOXNVkXrHhJFT936xGa8cW_1di36rsVBouVLEQ_LYgmr9UiPRHLj-RtZtxuZJq5zohOBH9s9GSftlxQYhzjcYg8EGilUP-P0Z7fDJ4XEVuVSXdnJ3_w5NRKfczQDKL_DVlkUPW4z22GPGqOEH7gJH7NBXj5hFz108WrBG3Rxiy6OkOHALbq4RRcndPG64g5dfIMu27VFF7fo4hZdvI-up2x-fDQ7nHhNcQ7vXKBR6oFA9U1ZrqMsXkRBmkkN4zBTuQaRhz5oERljQCgTSRMu0MyWJos0ZCYF6S-EfMa2y6rMnzMOyk99gzxWKD8Ak5k4NpGOUVMoKXGUXfbWvaPkm8vAktxHOrtsH19skhZ0RXuHHDOVipTCpSiUQr34r9Ffsocd3vfYdv19ne8jTa3NK4uG39o7m78
linkProvider ISSN International Centre
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Examination+of+Heating+Media+for+a+Metal+Oxide+Film+to+Create+Materials+for+Teaching+about+Light+Interference&rft.jtitle=Transactions+on+GIGAKU&rft.au=Ueno%2C+Takahisa&rft.au=Ninomiya%2C+Junko&rft.au=Tomiyoshi%2C+Ryota&rft.au=Hinago%2C+Kaname&rft.date=2022-07-29&rft.pub=Nagaoka+University+of+Technology&rft.eissn=2435-5895&rft.volume=9&rft.issue=2&rft.spage=09015-1&rft.epage=09015-9&rft_id=info:doi/10.34468%2Fgigaku.9.2_09015-1&rft.externalDocID=article_gigaku_9_2_9_09015_1_article_char_en