A low-temperature oxyl transfer to carbon monoxide from the ZnII–oxyl site in a zeolite catalyst

• Published in: Inorganic chemistry frontiers Vol. 8; no. 2; pp. 319 - 328
• Main Authors: Oda, Akira, Kumagai, Jun, Ohkubo, Takahiro, Kuroda, Yasushige
• Format: Journal Article
• Language: English; Japanese
• Published: London Royal Society of Chemistry 01.01.2021
• Subjects: Carbon monoxide; Catalysts; Inorganic chemistry; Low temperature; Spectroscopy; Zeolites

An atomic O radical anion bound to a metal ion (metal–oxyl) is a key intermediate in a variety of oxidative reactions. Understanding its structure–reactivity relationship is highly desirable for the rational design of challenging oxidative transformation processes. However, due to the difficulty of...