Experimental Evidence for a Jahn-Teller Distortion in AuCl3
Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine J...
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| Published in | Angewandte Chemie Vol. 117; no. 41; pp. 6904 - 6908 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
21.10.2005
WILEY‐VCH Verlag |
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| Abstract | Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine Jahn‐Teller‐verzerrte T‐förmige Geometrie hat (siehe Bild). |
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| AbstractList | Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine Jahn‐Teller‐verzerrte T‐förmige Geometrie hat (siehe Bild). |
| Author | Harris, Neil Thompson, Emma L. Holdaway, Mark A. Rooms, John F. Bridgeman, Adam J. Blackmore, Ian J. Young, Nigel A. |
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| Notes | ArticleID:ANGE200502503 This work was supported by the Engineering and Physical Sciences Research Council UK (EPSRC-GR/T09651) and the University of Hull. istex:56522B3CFE58FFD768B2A011BFFE813325D802E4 ark:/67375/WNG-7DR7WXFX-2 This work was supported by the Engineering and Physical Sciences Research Council UK (EPSRC‐GR/T09651) and the University of Hull. |
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| SubjectTerms | Dichtefunktionalrechnungen EXAFS-Spektroskopie Gold Jahn-Teller-Verzerrung Matrixisolation |
| Title | Experimental Evidence for a Jahn-Teller Distortion in AuCl3 |
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