Experimental Evidence for a Jahn-Teller Distortion in AuCl3
Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine J...
Saved in:
Published in | Angewandte Chemie Vol. 117; no. 41; pp. 6904 - 6908 |
---|---|
Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
21.10.2005
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine Jahn‐Teller‐verzerrte T‐förmige Geometrie hat (siehe Bild). |
---|---|
AbstractList | Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten die ersten experimentellen Belege dafür, dass die Grundzustandsstruktur von AuCl3 nicht D3h‐symmetrisch (trigonal‐planar) ist, sondern eine Jahn‐Teller‐verzerrte T‐förmige Geometrie hat (siehe Bild). |
Author | Harris, Neil Thompson, Emma L. Holdaway, Mark A. Rooms, John F. Bridgeman, Adam J. Blackmore, Ian J. Young, Nigel A. |
Author_xml | – sequence: 1 givenname: Ian J. surname: Blackmore fullname: Blackmore, Ian J. organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 2 givenname: Adam J. surname: Bridgeman fullname: Bridgeman, Adam J. organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 3 givenname: Neil surname: Harris fullname: Harris, Neil organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 4 givenname: Mark A. surname: Holdaway fullname: Holdaway, Mark A. organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 5 givenname: John F. surname: Rooms fullname: Rooms, John F. organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 6 givenname: Emma L. surname: Thompson fullname: Thompson, Emma L. organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 – sequence: 7 givenname: Nigel A. surname: Young fullname: Young, Nigel A. email: n.a.young@hull.ac.uk organization: Department of Chemistry, The University of Hull, Kingston upon Hull, HU6 7RX, UK, Fax: (+44) 1482-466-410 |
BookMark | eNo9kE1PAjEURRuDiYBuXfcPFF-_pp24IjCghmBiSGDXtEOr1bFDZlDh3zsGw-rmLc7LPXeAeqlOHqFbCiMKwO5sevUjBiCBSeAXqE8lo4QrqXqoDyAE0UzkV2jQtu8AkDGV99F9cdj5Jn76tLcVLr7j1qfS41A32OIn-5bIyleVb_A0tvu62cc64Zjw-GtS8Wt0GWzV-pv_HKLVrFhNHsjief44GS9I1JoTpa2Sebb1joKSTFDKQgDqOFeCCsaF1AFKYZ2zypVeB-2cz4PMpJS03HI-RPnp7U-s_NHsura2ORoK5k_b_Gmbs7YZL-fF-epYcmK79v5wZm3zYTLVTWPWy7lR0xe13sw2hvFf9uxd9Q |
ContentType | Journal Article |
Copyright | Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
Copyright_xml | – notice: Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
DBID | BSCLL |
DOI | 10.1002/ange.200502503 |
DatabaseName | Istex |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1521-3757 |
EndPage | 6908 |
ExternalDocumentID | ANGE200502503 ark_67375_WNG_7DR7WXFX_2 |
Genre | shortCommunication |
GroupedDBID | -~X .3N .GA .Y3 05W 0R~ 10A 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4.4 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5VS 66C 6P2 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABEML ABHUG ABIJN ABJNI ABLJU ABPVW ACAHQ ACBWZ ACCFJ ACCUC ACCZN ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXME ADAWD ADBBV ADDAD ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFRAH AFVGU AGJLS AHBTC AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ASPBG ATUGU AUFTA AVWKF AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BSCLL BY8 CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBS EJD F00 F01 F04 F5P FEDTE G-S G.N GNP GODZA H.T H.X HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LITHE LOXES LP6 LP7 LUTES LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ O66 O9- P2W P2X P4D Q.N Q11 QB0 QRW R.K RGC ROL RWI RX1 SUPJJ TN5 UB1 UPT V2E W8V W99 WBFHL WBKPD WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XV2 Y6R ZZTAW ~IA ~WT ACXQS AITYG HGLYW OIG |
ID | FETCH-LOGICAL-i883-78a7596deb107524112ff01b33741423458f0c4abba7bce8f8bbe9f565551cd33 |
IEDL.DBID | DR2 |
ISSN | 0044-8249 |
IngestDate | Sat Aug 24 00:59:44 EDT 2024 Wed Jan 17 05:00:29 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 41 |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-i883-78a7596deb107524112ff01b33741423458f0c4abba7bce8f8bbe9f565551cd33 |
Notes | ArticleID:ANGE200502503 This work was supported by the Engineering and Physical Sciences Research Council UK (EPSRC-GR/T09651) and the University of Hull. istex:56522B3CFE58FFD768B2A011BFFE813325D802E4 ark:/67375/WNG-7DR7WXFX-2 This work was supported by the Engineering and Physical Sciences Research Council UK (EPSRC‐GR/T09651) and the University of Hull. |
PageCount | 5 |
ParticipantIDs | wiley_primary_10_1002_ange_200502503_ANGE200502503 istex_primary_ark_67375_WNG_7DR7WXFX_2 |
PublicationCentury | 2000 |
PublicationDate | 2005-10-21 October 21, 2005 |
PublicationDateYYYYMMDD | 2005-10-21 |
PublicationDate_xml | – month: 10 year: 2005 text: 2005-10-21 day: 21 |
PublicationDecade | 2000 |
PublicationPlace | Weinheim |
PublicationPlace_xml | – name: Weinheim |
PublicationTitle | Angewandte Chemie |
PublicationTitleAlternate | Angewandte Chemie |
PublicationYear | 2005 |
Publisher | WILEY-VCH Verlag WILEY‐VCH Verlag |
Publisher_xml | – name: WILEY-VCH Verlag – name: WILEY‐VCH Verlag |
References | A. Schulz, M. Hargittai, Chem. Eur. J. 2001, 7, 3657. D. B. Dell'Amico, F. Calderazzo, F. Marchetti, J. Chem. Soc. Dalton Trans. 1976, 1829 P. Schwerdtfeger, P. D. W. Boyd, S. Brienne, A. K. Burrell, Inorg. Chem. 1992, 31, 3411. D. B. Dell'Amico, F. Calderazzo, F. Marchetti, S. Merlino, G. Perego, J. Chem. Soc. Chem. Commun. 1977, 31. S. Seidel, K. Seppelt, Science 2000, 290, 117 P. Pyykkö, Angew. Chem. 2004, 116, 4512 A. van der Gaauw, O. M. Wilkin, N. A. Young, J. Chem. Soc. Dalton Trans. 1999, 2405. M. L. Munzarova, R. Hoffmann, J. Am. Chem. Soc. 2002, 124, 5542. Refined Au L3-edge EXAFS parameters. AuCl3 (rAuCl, 2.224(5) Å; 2σ2, 0.007(1); Ef, −8.1(12), R, 41.1 %). H[AuCl4]⋅3 H2O (rAuCl, 2.282(2) Å; 2σ2, 0.006(1); Ef, −11.7(4), R, 19 %). The literature rAuCl values for H[AuCl4]⋅4 H2O are 2.283 and 2.286 Å (J. M. Williams, S. W. Peterson, J. Am. Chem. Soc. 1969, 91, 776). R. K. Bellingham, J. T. Graham, P. J. Jones, J. R. Kirby, W. Levason, J. S. Ogden, A. K. Brisdon, E. G. Hope, J. Chem. Soc. Dalton Trans. 1991, 3387. D. Schröder, R. Brown, P. Schwerdtfeger, X. B. Wang, X. Yang, L. S. Wang, H. Schwarz, Angew. Chem. 2003, 115, 323 Angew. Chem. Int. Ed. 2004, 43, 4412. A. Laguna, M. Laguna, Coord. Chem. Rev. 1999, 195, 837. D. M. Gruen, S. L. Gaudioso, R. L. McBeth, J. L. Lerner, J. Chem. Phys. 1974, 60, 89 A. J. Bridgeman, G. Cavigliasso, N. Harris, N. A. Young, Chem. Phys. Lett. 2002, 351, 319. D. M. Gruen, J. K. Bates, Inorg. Chem. 1977, 16, 2450. Angew. Chem. Int. Ed. 2002, 41, 454 K. Seppelt, Z. Anorg. Allg. Chem. 2003, 629, 2427. Angew. Chem. Int. Ed. 2003, 42, 4442. T. Drews, S. Seidel, K. Seppelt, Angew. Chem. 2002, 114, 470 B. Réffy, M. Kolonits, A. Schulz, T. M. Klapötke, M. Hargittai, J. Am. Chem. Soc. 2001, 123, 1545. N. R. Walker, R. R. Wright, P. E. Barran, J. N. Murrell, A. J. Stace, J. Am. Chem. Soc. 2001, 123, 4223 Angew. Chem. Int. Ed. 2003, 42, 311. J. H. Choy, Y. I. Kim, S. J. Hwang, P. V. Huong, J. Phys. Chem. B 2000, 104, 7273. G. te Velde, F. M. Bickelhaupt, E. J. Baerends, C. Fonseca Guerra, S. J. A. van Gisbergen, J. G. Snijders, T. Ziegler, J. Comput. Chem. 2001, 22, 931 D. S. Rustad, N. W. Gregory, Polyhedron 1991, 10, 633 H. Schwarz, Angew. Chem. 2003, 115, 4580 N. R. Walker, R. R. Wright, P. E. Barran, A. J. Stace, Organometallics 1999, 18, 3569. T. Sohnel, R. Brown, L. Kloo, P. Schwerdtfeger, Chem. Eur. J. 2001, 7, 3167. L. Nalbandian, S. Boghosian, G. N. Papatheodorou, Inorg. Chem. 1992, 31, 1769. M. Hargittai, A. Schulz, B. Réffy, M. Kolonits, J. Am. Chem. Soc. 2001, 123, 1449. J. H. Choy, Y. I. Kim, J. Phys. Chem. B 2003, 107, 3348. B. Réffy, M. Kolonits, A. Schulz, T. M. Klapötke, M. Hargittai, J. Am. Chem. Soc. 2000, 122, 3127. D. Schröder, J. Hrusák, I. C. Tornieporth-Oetting, T. M. Klapötke, H. Schwarz, Angew. Chem. 1994, 106, 223 Angew. Chem. Int. Ed. Engl. 1994, 33, 212. C. Fonseca Guerra, J. G. Snijders, G. te Velde, E. J. Baerends, Theor. Chem. Acc. 1998, 99, 391 L. Nalbandian, G. N. Papatheodorou, Vib. Spectrosc. 1992, 4, 25. 2000 2002 2002 2003; 290 114 41 629 2001; 123 2004 2004; 116 43 2003 2003; 115 42 2003; 107 1991 1992; 10 31 2001 1999; 123 18 2001; 7 2002; 351 1969; 91 2000; 104 2002; 124 1974 1977; 60 16 1998 2001; 99 22 1999; 195 1976 1977 1994 1994; 106 33 2000; 122 1991 1992; 31 1992; 4 1999 |
References_xml | – volume: 107 start-page: 3348 year: 2003 publication-title: J. Phys. Chem. B – volume: 115 42 start-page: 323 311 year: 2003 2003 publication-title: Angew. Chem. Angew. Chem. Int. Ed. – volume: 106 33 start-page: 223 212 year: 1994 1994 publication-title: Angew. Chem. Angew. Chem. Int. Ed. Engl. – volume: 60 16 start-page: 89 2450 year: 1974 1977 publication-title: J. Chem. Phys. Inorg. Chem. – volume: 31 start-page: 3411 year: 1992 publication-title: Inorg. Chem. – start-page: 3387 year: 1991 publication-title: J. Chem. Soc. Dalton Trans. – volume: 123 18 start-page: 4223 3569 year: 2001 1999 publication-title: J. Am. Chem. Soc. Organometallics – volume: 7 start-page: 3657 year: 2001 publication-title: Chem. Eur. J. – start-page: 2405 year: 1999 publication-title: J. Chem. Soc. Dalton Trans. – volume: 123 start-page: 1449 year: 2001 publication-title: J. Am. Chem. Soc. – volume: 104 start-page: 7273 year: 2000 publication-title: J. Phys. Chem. B – volume: 122 start-page: 3127 year: 2000 publication-title: J. Am. Chem. Soc. – volume: 10 31 start-page: 633 1769 year: 1991 1992 publication-title: Polyhedron Inorg. Chem. – volume: 290 114 41 629 start-page: 117 470 454 2427 year: 2000 2002 2002 2003 publication-title: Science Angew. Chem. Angew. Chem. Int. Ed. Z. Anorg. Allg. Chem. – volume: 7 start-page: 3167 year: 2001 publication-title: Chem. Eur. J. – start-page: 1829 31 year: 1976 1977 publication-title: J. Chem. Soc. Dalton Trans. J. Chem. Soc. Chem. Commun. – volume: 4 start-page: 25 year: 1992 publication-title: Vib. Spectrosc. – volume: 116 43 start-page: 4512 4412 year: 2004 2004 publication-title: Angew. Chem. Angew. Chem. Int. Ed. – volume: 91 start-page: 776 year: 1969 publication-title: J. Am. Chem. Soc. – volume: 123 start-page: 1545 year: 2001 publication-title: J. Am. Chem. Soc. – volume: 124 start-page: 5542 year: 2002 publication-title: J. Am. Chem. Soc. – volume: 99 22 start-page: 391 931 year: 1998 2001 publication-title: Theor. Chem. Acc. J. Comput. Chem. – volume: 195 start-page: 837 year: 1999 publication-title: Coord. Chem. Rev. – volume: 115 42 start-page: 4580 4442 year: 2003 2003 publication-title: Angew. Chem. Angew. Chem. Int. Ed. – volume: 351 start-page: 319 year: 2002 publication-title: Chem. Phys. Lett. |
SSID | ssj0006279 |
Score | 1.6248926 |
Snippet | Daten aus der Matrixisolations‐IR‐Spektroskopie, der elektronischen Absorption und der Au‐L3‐Kanten‐EXAFS (extended X‐ray absorption fine structure) lieferten... |
SourceID | wiley istex |
SourceType | Publisher |
StartPage | 6904 |
SubjectTerms | Dichtefunktionalrechnungen EXAFS-Spektroskopie Gold Jahn-Teller-Verzerrung Matrixisolation |
Title | Experimental Evidence for a Jahn-Teller Distortion in AuCl3 |
URI | https://api.istex.fr/ark:/67375/WNG-7DR7WXFX-2/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fange.200502503 |
Volume | 117 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpZ07T8MwEMct1AUW3oi3PCC2tI7tJO7AUPWFKtGhKmq2yHZtURUFVFoJMfEd-IZ8Es5Jk7aMMEayJeti3_1zOf8OoRtfEoiCRngM4onHpTUenCKHceUB0SHRVrs_ug_98P6R9-IgXrvFn_MhyoSbOxmZv3YHXKq32goa6mrvs5yIi-IO9-loek4VDVb8qJDmsD3CuSfgQ6OgNhJa25wO0tRZ9X1TomYxprOHZLG6vLRkWl3MVVV__AI3_mf5-2h3KUBxI98xB2jLpIdou1n0fTtCd-016D8uuo5iELdY4p58Sr8_v4Yu3T_DrYwx4l4tnqS4sWg-s2M07LSHzXtv2WTBmwjBvEjIKKiHY3DZIB4gnPvUWuIrxkBqgNTigbBEc6mUjJQ2wgqlTN2CDASppceMnaBK-pKaU4SZgSjoawMuQ3LrUzUGaVenRNMoVFbTM3Sb2Th5zTkaiZxNXVlZFCSjfjeJWoNoFHfiBAbSzHLlwBytTBNns6S0WdLod9vl0_lfJl2gnQLFSv1LVJnPFuYKRMZcXWcb6Qe3scg2 |
link.rule.ids | 315,786,790,1382,27955,27956,46327,46751 |
linkProvider | Wiley-Blackwell |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpZ07T8MwEMctKENZeCPeeEBsaRM7rw4MVZ-UNkNV1G6W7dqiKgqoaiXExHfgG_JJOCdNShlhjGRLycXn--dy_h1CNw63IQqq0KIQTyyXa2WBFxmMq-vZ0relluaPbi_y249uZ-Rl1YTmLEzKh8gTbsYzkv3aOLhJSJdX1FBTfJ8kRUwYp5toC3zeM75Z768IUj5JcXu261ohfGpk3EablNfngzg1dn1bF6lJlGnuIpHdX1pcMi0t5qIk33-hG__1AHtoZ6lBcTVdNPtoQ8UHqFjLWr8dorvGD-4_zhqPYtC3mOMOf4q_Pj4HJuM_w_UEM2LeLp7EuLqoPdMjNGg2BrW2teyzYE3CkFpByAOv4o9h1wb9ABHdIVrbjqAU1AaoLdcLtS1dLgQPhFShDoVQFQ1KENSWHFN6jArxS6xOEKYKAqEjFewa3NUOEWNQdxViSxL4Qktyim4TI7PXFKXB-GxqKssCjw2jFgvq_WA4ao4YDCSJ6fKBKV2ZMGMzltuMVaNWI786-8uka1RsD3pd1r2PHs7RdkZmJc4FKsxnC3UJmmMurpJV9Q1nA8xW |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpZ1LSwMxEMeDVlAvvsW3OYi3bXeT7KMHD6UPa9UipdLeQpImWCprKS2IJ7-D39BP4mS324dHPS4kEGYzM_9kZ3-D0JUnXMiCOnIo5BOHCaMd8CKLcWW-qwJXGWW_6D42g_oza3T97sJf_CkfYnbhZj0jidfWwYc9U5hDQ23tfXInYrM4XUVrLKDEHr8qrTlAKiApbc9lzIngpJFhG11SWJ4P2tSa9X1ZoyZJpraNRLa8tLZkkJ-MZV59_CI3_mf9O2hrqkBxKd0yu2hFx3too5w1fttHN9UF6j_O2o5iULdY4IZ4ib8_v9r2vn-EKwlkxL5b3I9xaVJ-pQeoXau2y3Vn2mXB6UcRdcJIhH4x6EHMBvUA-dwjxriepBS0Bmgt5kfGVUxIKUKpdGQiKXXRgA4EraV6lB6iXPwW6yOEqYY06CkNMUMw4xHZA21XJK4iYSCNIsfoOrExH6YgDS5GA1tXFvq807zlYaUVdrq1LoeBJLHcbGDKVibc2ozPbMZLzdvq7OnkL5Mu0fpTpcYf7pr3p2gzw7IS7wzlxqOJPgfBMZYXyZ76ASWSywU |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Experimental+Evidence+for+a+Jahn-Teller+Distortion+in+AuCl3&rft.jtitle=Angewandte+Chemie&rft.au=Blackmore%2C+Ian+J.&rft.au=Bridgeman%2C+Adam+J.&rft.au=Harris%2C+Neil&rft.au=Holdaway%2C+Mark+A.&rft.date=2005-10-21&rft.pub=WILEY-VCH+Verlag&rft.issn=0044-8249&rft.eissn=1521-3757&rft.volume=117&rft.issue=41&rft.spage=6904&rft.epage=6908&rft_id=info:doi/10.1002%2Fange.200502503&rft.externalDBID=n%2Fa&rft.externalDocID=ark_67375_WNG_7DR7WXFX_2 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0044-8249&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0044-8249&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0044-8249&client=summon |